Research Article

The Effect of Pre-Veraison Smoke Exposure of Grapes on Phenolic Compounds and Smoky Flavour in Wine

Table 2

Phenolic analytes concentration (μg/kg) in grapes sampled at pre-veraison.

CultivarVineyard†Bwt (g)SyGGMSyGGPhRGGuRGCrRGMGuRGGuo-cresolm-cresol

ChardonnayA0.47 ± 0.031.9 ± 0.30<LoQ<LoQ<LoQ1.3 ± 0.20<LoQ<LoQ<LoQ<LoQ
B‡0.39 ± 0.012.3 ± 0.10<LoQ<LoQ<LoQ1.1 ± 0.10<LoQ<LoQ1.0 ± 1.0<LoQ
C0.43 ± 0.0275 ± 2.711 ± 1.51.7 ± 0.72.9 ± 0.103.4 ± 0.205.2 ± 1.3<LoQ2.0 ± 2.0<LoQ
D0.45 ± 0.132.3 ± 0.30<LoQ<LoQ<LoQ1.6 ± 0.60<LoQ<LoQ1.0 ± 1.0<LoQ
E0.55 ± 0.0213 ± 2.51.2 ± 0.10<LoQ1.0 ± 0.201.5 ± 0.501.4 ± 0.6<LoQ1.0 ± 1.0<LoQ
G0.40 ± 0.01120 ± 4315 ± 3.74.4 ± 3.67.3 ± 2.86.4 ± 3.311 ± 3.81.7 ± 1.53.0 ± 2.61.7 ± 1.5
J0.41 ± 0.01160 ± 4314 ± 4.23.5 ± 1.45.2 ± 1.46.9 ± 0.807.4 ± 1.62.0 ± 1.04.0 ± 2.02.0 ± 1.0
K0.48 ± 0.0121 ± 5.01.9 ± 0.201.3 ± 0.61.6 ± 0.202.1 ± 0.201.8 ± 0.2<LoQ1.3 ± 1.2<LoQ

Pinot noirA0.41 ± 0.021.3 ± 0.20<LoQ<LoQ1.2 ± 0.101.7 ± 0.20<LoQ<LoQ<LoQ<LoQ
B‡0.39 ± 0.021.0 ± 0.10<LoQ<LoQ<LoQ1.1 ± 0.20<LoQ<LoQ<LoQ<LoQ
C0.39 ± 0.0529 ± 6.02.4 ± 0.603.0 ± 2.05.0 ± 1.44.0 ± 1.03.4 ± 1.5<LoQ1.3 ± 1.2<LoQ
D0.37 ± 0.021.9 ± 0.10<LoQ1.1 ± 0.6<LoQ1.6 ± 0.20<LoQ<LoQ<LoQ<LoQ
E0.55 ± 0.0412 ± 4.2<LoQ1.5 ± 0.91.8 ± 0.602.6 ± 0.701.3 ± 0.6<LoQ<LoQ<LoQ
G0.38 ± 0.0496 ± 226.9 ± 1.313 ± 5.222 ± 3.019 ± 2.116 ± 1.81.0 ± 1.02.3 ± 1.51.0 ± 1.0
H0.45 ± 0.0481 ± 184.8 ± 0.9014 ± 1014 ± 1.419 ± 4.711 ± 5.01.3 ± 1.23.7 ± 2.31.3 ± 1.2
L0.43 ± 0.0455 ± 4.75.1 ± 1.410 ± 6.613 ± 1.013 ± 2.18.0 ± 3.41.0 ± 1.02.7 ± 1.5<LoQ

ShirazA‡0.43 ± 0.041.8 ± 0.05<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ
B0.38 ± 0.021.8 ± 0.28<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ
C0.41 ± 0.0051 ± 6.18.7 ± 0.981.0 ± 0.302.6 ± 0.102.4 ± 0.404.4 ± 0.902.0 ± 2.01.7 ± 1.5<LoQ
D0.44 ± 0.052.9 ± 0.44<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ<LoQ
F0.48 ± 0.0437 ± 7.15.8 ± 1.9<LoQ2.1 ± 0.21.6 ± 0.503.0 ± 1.41.7 ± 1.51.0 ± 1.0<LoQ
G0.36 ± 0.07120 ± 5321 ± 8.62.5 ± 1.67.5 ± 5.15.9 ± 3.714 ± 8.12.0 ± 1.01.7 ± 1.5<LoQ
I0.33 ± 0.0594 ± 1116 ± 2.22.0 ± 0.704.8 ± 0.304.6 ± 0.47.6 ± 2.02.7 ± 0.581.3 ± 1.2<LoQ
K0.35 ± 0.0451 ± 3.19.6 ± 1.31.2 ± 0.403.5 ± 0.403.0 ± 0.505.0 ± 1.62.3 ± 0.601.7 ± 1.2<LoQ

Mean values ± standard deviation (n = 3). All phenolic glycoside values are expressed as syringol gentiobioside equivalents. Bwt, berry weight; Ph, phenol; Gu, guaiacol; Cr, cresol; Sy, syringol; MGu, 4-methylguaiacol; MSy, 4-methylsyringol; GG, gentiobiosides; RG, rutinoside; LoQ, limit of quantitation = 1 μg/kg. Values for the analytes, 4-methylguaiacol, p-cresol, syringol and 4-methylsyringol were below LoQ for all samples. †: for details of vineyard code, see Table 1. ‡: control block selected for comparison; : significantly higher than selected control using Dunnett’s means comparison test ().