Research Article

Investigating the Effects of Nonsolvent Additive and Spinning Conditions on Morphology and Permeation of PAN Hollow Fiber Membranes

Table 1

State of the art for PAN hollow fiber membrane.

Dope chemical compositionApplicationInvestigated parametersReference

PAN/DMF: 15/85UltrafiltrationSolvent amount in coagulation bath, draw ratio (take-up speed)[34]
PAN/DMF/PEG: 22/78/0-30PervaporationPosttreatment with a water bath, a dry air oven heat-treatment, PEG content, PEG molecular weight[35]
PAN/DMF: 22/78PervaporationHeat-treatment temperature, feed composition, feed solution temperature[36]
PAN/PVP/ZnCl2/DMF: 15-20/0-0.5/0-3/80-82UltrafiltrationFlow rate of polymer dope, bore liquid, polymer concentration, speed of polymer pump, feed pressure[37]
Self-made PAN HFMs
membranes)MWCO 60000 Da)
Packing in distillationHeat treatment time and temperature, thermal and chemical stability in solvents[38]
PAN/CaCl2/DMF: 18/1/81UltrafiltrationPAN/LiCl and PAN/CaCl2 ratios[39]
PAN/PVP1100-1400 kDa/NMP: 8-12/2-6/86UltrafiltrationVirus filtration, fouling[40]
Purchased PAN HFM (MWCO: 60 000 Da)Gas separationChemical modification provided by a covalent linker between the MOF layer and PAN substrate, chemical and mechanical stability[41]
PAN/PVP K30/DMSO: 17.0/4.0/79.0UltrafiltrationDope composition, bore fluid, dope flow rate, bore fluid flow rate, take-up speed[42]
PAN/PVP 360 K/DMF/propane diol: 18/78/3/1UltrafiltrationAir gap, modification with hypochlorite[43]