Effect of Ce Addition on Adsorption and Oxidation of NO over MnO<svg xmlns:xlink="http://www.w3.org/1999/xlink" xmlns="http://www.w3.org/2000/svg" style="vertical-align:-4.34426pt" id="M1" height="5.77417pt" version="1.1" viewBox="-0.0657574 -1.42991 7.64947 5.77417" width="7.64947pt"><g transform="matrix(.012,0,0,-0.012,0,4.134)"><path id="g50-121" d="M545 403C545 425 527 451 498 451C448 451 400 404 312 286L290 341C262 412 246 451 219 451C182 451 138 404 92 345L112 323C152 368 169 378 181 378C192 378 201 359 216 321L257 214C184 115 142 69 113 69C102 69 93 73 88 79S78 89 68 89C47 89 24 61 24 40C24 8 49 -12 75 -12C125 -12 175 31 271 175L312 64C330 15 357 -12 382 -12C421 -12 475 35 515 98L496 121C466 88 439 62 420 62C402 62 384 92 363 147L325 247C349 280 374 309 397 333C422 361 446 381 462 381C471 381 481 374 488 366C493 360 499 357 505 357C521 357 545 380 545 403Z"/></g></svg>/Al<sub>2</sub>O<sub>3</sub>

Mou, Chunhui; Li, Hui; Dong, Ning; Hui, Shien; Wang, Denghui

doi:https://doi.org/10.1155/2021/3131309

Adsorption Science & Technology

On this page

Abstract Introduction Experimental Results and Discussion Conclusions Data Availability Conflicts of Interest Acknowledgments References Copyright Related Articles

Special Issue

Adsorption in Air Pollution Control

View this Special Issue

Research Article | Open Access

Volume 2021 | Article ID 3131309 | https://doi.org/10.1155/2021/3131309

Effect of Ce Addition on Adsorption and Oxidation of NO over MnO/Al₂O₃

Chunhui Mou,¹Hui Li,²Ning Dong,²Shien Hui,²and Denghui Wang²

Academic Editor: Stefano Salvestrini

Received31 May 2021

Revised21 Aug 2021

Accepted26 Aug 2021

Published08 Sept 2021

Abstract

The MnO/Al₂O₃ catalysts with different Ce content doping were prepared by an ultrasonic impregnation method, and the catalytic activity for NO oxidation removal was tested in a fixed-bed quartz tube furnace. Simultaneously, the catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), full-automatic physical-chemical adsorption instrument, and field emission scanning electron microscope (FESEM) to analyze the effect of Ce addition on the adsorption capacity and catalytic activity. Experimental results validated that the activity of the MnO/Al₂O₃ catalyst was greatly promoted with Ce addition. According to the characterization results, it could be concluded that Ce doping led to significant changes in the crystalline phase on the catalyst surface, which increased the relative content of surface lattice oxygen and promoted the catalytic oxidation of NO. By observing the physical properties of the surface and analyzing the surface elements of the catalyst, it could be inferred that a manganese-cerium solid solution was formed on the surface of Mn_0.4Ce_0.05/Al. Moreover, Ce addition increased the catalyst pore size, which enhanced the adsorption and contact of NO and O₂ with the active sites on the catalyst surface, and reduced the resistance of the reactants during internal diffusion. All these variations assigned to Mn_0.4Ce_0.05/Al were favorable for the catalytic oxidation of NO.

1. Introduction

The combustion of massive fossil fuels brings about the harmful emission of nitrogen oxides (NO). The problem has attracted great attention in recent decades, for the close relationship between NO and many serious environmental issues, including acid rain, city photochemical smog, and tropospheric ozone depletion [1–4]. To reduce the poisonous NO emissions, many techniques have been researched and applied to thermal power plants and diesel engines. Reductive denitration technology has been extensively researched, including selective catalytic reduction (SCR) and selective noncatalytic reduction (SNCR). Due to its high efficiency, SCR has always been regarded as an effective method to remove fixed emission sources such as power plants [5–8]. In the common SCR process, injected NH₃ reduces noxious NO to harmless N₂ with the aid of efficient catalysts. The typical reactions are as follows [9, 10].

NH₃-SCR has also exposed many problems in a wide range of industrial applications, such as high investment and operating costs, NH₃ escape, N₂O generation, and catalyst deactivation [11, 12]. The greenhouse effect of N₂O is up to 300 times that of carbon dioxide. The almost inevitable escape of NH₃ is particularly worrying. It not only increases the operation cost but also easily results in serious air preheater blocking. Therefore, how to remove NO from coal-burning exhaust gas with low cost, pollution-free, and high efficiency has become a research focus. Recently, NO catalytic oxidation removal is drawing much attention for its getting rid of NH₃ during NO removal [13–15]. Although over 90% of NO formed in fuel combustion is insoluble NO, its oxidation product NO₂ is rather soluble. Therefore, with the participation of catalysts, it is feasible to use the remaining O₂ in the flue gas to oxidize NO to NO₂, which is then captured by alkali liquor in a wet flue gas desulfurization plant [11, 16, 17].

Although many noble metal catalysts have shown good performance in NO catalytic oxidation, the high cost limits their wide application in coal-fired power plants [18–20]. Transition metal oxides have been proven with excellent performance compared to noble metal catalysts, with a wide range of sources, low prices, simple preparation processes, and good thermal stability. Therefore, they have received extensive and in-depth research in recent years [21–23]. Wu et al. prepared a series of MnO/TiO₂ composite nanoxides by deposition-precipitation method, and the sample with the Mn/Ti ratio of 0.3 showed a superior activity for NO oxidation, reaching 89% at 250°C [24]. Mn-based catalysts impregnated on TiO₂ with different crystalline phases were studied by An et al. for the oxidation of NO to NO₂, and 10% MnO/TiO₂ exhibited the highest efficiency 83% at 300°C [22]. The NO oxidation on Cu₂O with molecular oxygen, dissociated oxygen, and lattice oxygen was studied by Sun et al. using periodic density functional theory, and the Eley-Rideal mechanism was favored to explain the catalytic effect of Cu₂O on NO oxidation [25].

Active Al₂O₃ has the characteristics of large adsorption capacity, large specific surface area, good thermal stability, nontoxicity, and noncorrosiveness. Therefore, it is regarded as an excellent catalyst support material and has received extensive attention in the field of catalysis. Wang et al. [26] used a sol-gel method to prepare a series of Ce-based catalysts, selecting Co, Mn, Fe, Cr, and Ni as the doping metal elements. At a reaction temperature of 230°C, the order of NO catalytic activity is Co > Mn > Cr > Ni > Fe.

Although much work has been carried out on NO catalytic oxidation over transition metal oxides, there are some deficiencies along with these studies [21–25]. Firstly, only oxidation efficiency but not removal efficiency was focused on during the experiments. Secondly, the temperature window of the researched catalysts was relatively narrow, not suitable for large-scale practical application. In this investigation, we prepared a series of MnO/Al₂O₃ and Ce-doped MnO-CeO/Al₂O₃ catalysts and investigated the oxidation denitration performance of these catalysts. The effect of Ce doping on the catalyst physicochemical properties was discussed, and microcharacterization analysis was carried out to explore the key points affecting efficiency.

2. Experimental

2.1. Catalyst Preparation

All tested samples in the study were prepared via an ultrasonic impregnation method. Chemicals used here were of analytical grade. Firstly, 0.04 mol (10.04 g) Mn(NO₃)₂·4H₂O was dissolved in 20 mL deionized water. Afterwards, with continuous magnetic stirring, 0.1 mol (10.20 g) Al₂O₃ was added into the solution (; ). Then, the mixture experienced an ultrasonic oscillation lasting for 0.5 h to help to uniformly mix. After standing at room temperature overnight, the suspension was dried in an oven at 105°C for 12 h. The obtained solid product was calcined at 600°C for 5 h and then crushed and sieved to 60-80 mesh. Because the molar ratio of added Mn and Al was 0.4 in the sample, it was denoted as Mn_0.4/Al.

For samples with different Ce addition, a specific amount (0.005 mol, 0.01 mol, and 0.02 mol, respectively) of Ce(NO₃)₃·6H₂O was dissolved in deionized water with Mn(NO₃)₂·4H₂O together in the first preparation step. Other preparation procedures were the same as mentioned above. The finally prepared samples were denoted as Mn_0.4Ce_0.05/Al, Mn_0.4Ce_0.1/Al, and Mn_0.4Ce_0.2/Al, respectively.

2.2. Catalytic Activity Test

The catalyst activity test system is shown in Figure 1. The catalytic activity test was carried out in a fixed-bed quartz tube furnace. 0.5 g sample was fixed on the bottom of the quartz glass tube by quartz wool. The total gas flow rate was fixed to 1 L/min (STP), with 600 ppm NO, 8 vol% O₂, and balanced N₂. The exhaust gas after the reaction at a certain temperature was introduced into a 0.5 mol/L sodium hydroxide aqueous solution for absorption, after which the outlet gas composition was examined online by a Fourier transform infrared spectroscopy gas analyzer (Gasmet DX4000, Finland).

The NO removal efficiency was calculated according to the following equation:

2.3. Catalyst Characterization

N₂ adsorption-desorption measurement was performed on a full-automatic physical-chemical adsorption instrument (Micromeritics ASAP2020, USA) to determine the textural properties of samples. The specific surface area was acquired by the Brunauer-Emmett-Teller (BET) method, while the total pore volume and mean pore diameter were obtained according to the Barrett-Joyner-Halenda (BJH) method. The micromorphologies of samples were monitored by a field emission scanning electron microscope (FESEM, GeminiSEM 500, Germany). An X-ray diffraction (XRD) meter (Xpert pro, Netherlands) was adopted to identify the crystal phases of samples. The scanning angular velocity was 7°/min, and the scanning angle range was 20°-80°. An X-ray photoelectron spectroscopy (XPS, AXIS ULtrabld, UK) was employed to analyze the catalyst surface atomic concentrations, using C1s at 284.8 eV as the calibration.

3. Results and Discussion

3.1. Catalytic Activity

600 ppm NO, 8 vol% O₂, and balanced N₂ were introduced into the reactor to explore the performance of catalysts with different contents of active component Ce (Figure 2). As the reaction temperature increased from 20°C to 500°C, the NO removal efficiency was peaked at 400°C for all samples. The oxidation of NO to NO₂ is exothermic, and the reaction is limited by the thermodynamic equilibrium: the temperature rises, and the equilibrium shifts to the left. Therefore, the temperature increased, the NO oxidation rate decreased, and the denitration efficiency decreased. It was apparent that the removal efficiency of the Ce-doped Mn_0.4/Al catalyst was higher than that of the Ce-free Mn_0.4/Al catalyst, indicating the promotion effect of Ce addition on NO oxidation removal. In addition, the temperature window of Mn_0.4Ce/Al catalyst is wider than that of Mn_0.4/Al. The denitration efficiency of Mn_0.4Ce/Al at 300-450°C can be above 80%.

For the Mn_0.4/Al catalyst without Ce addition, the denitration efficiency increased gradually with the reaction temperature in 20-400°C, but it started to decrease slightly as the reaction temperature increased from 400°C to 500°C. The highest efficiency reached 79.5% at 400°C. When the molar ratio of Mn, Ce, and Al was 0.4 : 0.05 : 1, the efficiency reached the highest peak of 89.5%. When the molar ratio of Mn, Ce, and Al was 0.4 : 0.1 : 1, the efficiency peak reached 89.1%, similar to Mn_0.4Ce_0.05/Al. For Mn_0.4Ce_0.2/Al, the highest efficiency was 85.2%, a little lower than Mn_0.4Ce_0.05/Al and Mn_0.4Ce_0.1/Al. Doping with Ce improves the activity of the Mn/Al catalyst significantly. The temperature window moves to the left, indicating that the low-temperature activity of the catalyst is enhanced. Free Ce has excellent oxygen storage capacity, and a small amount of Ce doping increases the active sites on the catalyst surface, thereby increasing the NO removal rate. But excessive doping may aggravate the accumulation of surface crystals, cover some active centers, or block the pores, resulting in a decrease in the catalytic activity of the catalyst [27, 28]. In the subsequent surface analysis, it was found that after Ce doping, the specific surface area was significantly reduced. The active ingredient is not as much as possible and should be lower than the surface dispersion threshold. Otherwise, Ce agglomerates and stacks on the surface, so Mn_0.4Ce_0.05/Al with better activity is selected as the main research object in the follow-up.

3.2. XRD

The XRD patterns of Mn_0.4/Al and Mn_0.4Ce_0.05/Al expressing the crystal phases on the catalyst surface are depicted in Figure 3. MnO and CeO are the main research objects, so the Al₂O₃ carrier is not shown in Figure 3. There were only diffraction peaks corresponding to Mn₂O₃ in the XRD patterns of Mn_0.4/Al, indicating the well-crystallized Mn₂O₃ for Mn_0.4/Al catalysts. As for Mn_0.4Ce_0.05/Al, the diffraction peaks at 28.8°, 41.2°, and 67.2° were attributed to MnO₂, while the diffraction peaks at 28.9°, 36.5°, and 57.8° were ascribed to Mn₃O₄.

In the XRD patterns of Mn_0.4Ce_0.05/Al, the diffraction peaks of MnO₂ and Mn₃O₄ were very weak, and no diffraction peaks of Mn₂O₃ existed, which revealed that the addition of Ce had a great influence on the crystal structure of Mn_0.4/Al catalyst. It is worth noting that we also did not detect the crystalline phase of Ce in the XRD pattern, which indicated that Ce was evenly dispersed on the surface of the catalyst, or Ce enters the lattice of manganese. We speculate that Ce atoms may enter the lattice of Mn₂O₃, resulting in the disappearance of a large amount of Mn₂O₃ crystal structure on the catalyst surface and resulting in the increase of the crystal structure of MnO₂ and Mn₃O₄ on the catalyst surface.

After adding active component Ce to Mn_0.4/Al catalyst, manganese and cerium interacted in a solid solution manner, and manganese ions entered the cerium oxide lattice to increase the oxygen storage capacity of the cerium oxide and the oxygen migration activity of the surface oxide [29]. This interaction was related to the electron transfer between manganese and cerium and the gain and loss of oxygen, and it also influenced the crystal structure of the catalyst and the valence state of manganese and cerium compounds. Therefore, related characterization analysis was carried out.

3.3. XPS

The XPS spectra for Mn 2p of Mn_0.4/Al and Mn_0.4Ce_0.05/Al are separately drawn in Figure 4(a) and Figure 4(b). Mn2p peaks for Mn oxides have many multiplet-split components, and the binding energy of Mn⁴⁺ is greater than Mn³⁺ [30]. In Figure 4(a), the binding energy peaks of 641.0 eV and 652.5 eV represent Mn³⁺; the binding energy peaks at 642.8 eV and 653.4 eV represent Mn⁴⁺. The relative size of the energy spectrum peak area represents the relative content of different manganese oxides on the catalyst surface. The ratio and the ratio were 46.1% and 53.9%, respectively.

On Mn_0.4Ce_0.05/Al, the binding energy peaks of 641.3 eV and 652.8 eV represent Mn³⁺; the binding energy peaks at 642.8 eV and 654.2 eV represent Mn⁴⁺ in Figure 4(b). Compared with Mn0.4Ce0.05/Al, the energy level was shifted upward. The ratio and the ratio were 31.0% and 69.0%, respectively. The results indicated that partial Mn⁴⁺ converted to Mn³⁺ as a result of the addition of cerium. The increase of Mn³⁺ and the decrease of Mn⁴⁺ favored the catalyst oxidation activity, which was consistent with the results of Atribak et al. [31]. They also confirmed that the activity of Mn⁴⁺ for NO oxidation was lower than that of Mn³⁺.

Figure 5 shows the XPS spectra for O 1s of Mn_0.4/Al (Figure 5(a)) and Mn_0.4Ce_0.05/Al (Figure 5(b)). There were two kinds of oxygen in catalysts, i.e., surface absorbed oxygen (denoted as O) and lattice oxygen (denoted as O). In Figure 5(a), peaks at 532.9 and 531.6 eV were attributed to O, while the peak at 529.4 eV corresponded to O. And in Figure 5(b), peaks at 533.0 and 531.5 eV were attributed to O, while the peak at 529.3 eV corresponded to O. Although the binding energy for each peak showed few differences in Figure 5(a) and Figure 5(b), the intensity varied greatly, especially the relative intensity of O and O. The proportion of O to () in Figure 5(a) was as low as 20.4%, whereas the proportion in Figure 5(b) increased to 34.3%.

Lattice oxygen played an important role in NO oxidation. After adsorption on the catalyst surface, NO was first oxidized by the active lattice oxygen to form nitrite or nitrate on the surface of the catalyst [32]. The higher proportion of O signified the more lattice oxygen in catalysts, so Mn_0.4Ce_0.05/Al exhibited better catalytic oxidation activity than Mn_0.4/Al. Xiang et al. [33] built a model of manganese oxide loaded on alumina and analyzed the adsorption of NO and O₂ on the Mn/Al surface by density functional theory. Calculations have found that O₂ is not easy to stably adsorb on the Mn/Al surface, so the surface lattice oxygen O is more likely to participate in the oxidation of NO by the MvK mechanism. This was consistent with our experimental conclusions that the Mn_0.4Ce_0.05/Al catalyst with higher lattice oxygen content had a stronger ability to oxidize NO.

Figure 6 shows the XPS spectra for Ce 3d of Mn_0.4Ce_0.05/Al. The Ce 3d spectrum consists of two series of spin-orbit lines Ce3d_3/2 and Ce3d_5/2 [34]. There were eight distinct characteristic peaks, of which the peaks at 881.8 eV, 889.2 eV, 897.7 eV, 902.3 eV, 907.0 eV, and 916.0 eV correspond to Ce⁴⁺ [26, 35], and the peaks at 902.2 eV and 884.0 eV correspond to Ce³⁺ [36, 37]. It indicated that Ce in Mn_0.4Ce_0.05/Al had two forms of Ce⁴⁺ and Ce³⁺ after calcination at high temperature. The ratio and the ratio were 20.56% and 79.44%, respectively.

Ce had strong oxygen storage capacity and stores and releases oxygen through the transformation of Ce³⁺ and Ce⁴⁺, which was consistent with the higher lattice oxygen content on the surface of Mn_0.4Ce_0.05/Al. It can be seen from Figure 1 that Ce doping improved the low-temperature activity of the catalyst, which was consistent with the study of other scholars [38, 39]. In addition, the doping of Ce element led to a reduction in the amount of O atoms combined with Mn, which in turn converted Mn⁴⁺ to Mn³⁺ with better activity.

The results of the XPS characteristics of Mn_0.4/Al and Mn_0.4Ce_0.05/Al are listed in Table 1. According to the analysis above, the increase of Mn³⁺ and lattice oxygen was important for the effective improvement of catalyst activity.

The physical properties of Mn_0.4/Al and Mn_0.4Ce_0.05/Al are listed in Table 2, mainly including the BET surface area, the BJH pore volume, and the BJH average pore diameter. From Table 2, it could be found that the surface area and the pore volume of the Mn_0.4Ce_0.05/Al catalyst were lower than those of the Mn_0.4/Al catalyst. On the contrary, the pore diameter of the Mn_0.4Ce_0.05/Al catalyst was higher.

According to the XRD analysis results, cerium ions entered the manganese oxide lattice, resulting in an increase in the weight per unit volume of the pore structure and resulting in the decrease in the specific surface area and pore volume of the catalyst [40]. And it could be found in Table 1 that the O of Mn_0.4Ce_0.05/Al catalyst was less than that of Mn_0.4/Al. The decrease of O was probably because of the decrease of the catalyst pore volume. Larger pore size will enhance the contact of NO and O₂ with the active sites on the catalyst surface and reduce the resistance of the reactants during internal diffusion, so Mn_0.4Ce_0.05/Al exhibits stronger NO removal performance.

3.4. FESEM

The FESEM images with magnification times (×10000) of Mn_0.4/Al and Mn_0.4Ce_0.05/Al are shown in Figure 7. As shown in Figure 7(a), the Mn_0.4/Al surface was evenly distributed with fine particles. According to the above XRD analysis results, they were likely to be Mn₂O₃ particles. As shown in Figure 7(b), there were many needle-like substances on the Mn_0.4Ce_0.05/Al surface. The surface of Mn_0.4Ce_0.05/Al was rougher, which was conducive to generating more active sites and also conducive to the adsorption of reactants, which strengthens the catalytic oxidation of NO on the surface.

(a)

(b)

4. Conclusions

The NO oxidation removal activity of Mn_0.4/Al catalysts with different Ce contents (Mn_0.4/Al, Mn_0.4Ce_0.05/Al, Mn_0.4Ce_0.1/Al, and Mn_0.4Ce_0.2/Al) was studied experimentally. The results showed that the activity of Mn_0.4/Al catalysts was effectively promoted with Ce addition, and the Mn_0.4Ce_0.05/Al performed the best.

Simultaneously, the physical-chemical properties and microstructures of Mn_0.4/Al and Mn_0.4Ce_0.05/Al were compared and analyzed by various characterization methods, which was helpful to reveal the mechanism of catalytic oxidation of NO by Mn-based catalysts and the effect of Ce addition. The characterization results showed that (1) the entry of cerium ions into the manganese oxide lattice led to the change of crystal structure of the catalyst surface and the decrease of specific surface area and pore volume; (2) the decrease of Mn⁴⁺ and the increase of Mn³⁺ on the catalyst surface were beneficial to the NO oxidation; (3) Ce doping increased the lattice oxygen content on the surface of the Mn_0.4Ce_0.05/Al, which was favorable for NO oxidation.

Data Availability

All data, models, and code generated or used during the study appear in the submitted article.

Conflicts of Interest

The authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

Acknowledgments

The present work was supported by the National Natural Science Foundation of China (51906193).

References

C. Zhou, Y. Wang, Q. Jin, Q. Chen, and Y. Zhou, “Mechanism analysis on the pulverized coal combustion flame stability and NO_x emission in a swirl burner with deep air staging,” Journal of the Energy Institute, vol. 92, no. 2, pp. 298–310, 2019.
View at: Publisher Site | Google Scholar
X. Jin and Y. Zhou, “Numerical analysis on microscopic characteristics of pulverized coal moderate and intense low-oxygen dilution combustion,” Energy & Fuels, vol. 29, no. 5, pp. 3456–3466, 2015.
View at: Publisher Site | Google Scholar
S. Li, Y. Ge, and X. Wei, “Modeling NO and SO₂ oxidation by H₂O₂ in coal-fired flue gas,” Journal of Environmental Engineering, vol. 144, no. 11, p. 04018113, 2018.
View at: Publisher Site | Google Scholar
S. Li, Y. Ge, and X. Wei, “Experiment on NO_x reduction by advanced reburning in cement precalciner,” Fuel, vol. 224, pp. 235–240, 2018.
View at: Publisher Site | Google Scholar
G. Madia, M. Koebel, M. Elsener, and A. Wokaun, “The effect of an oxidation precatalyst on the NO_x reduction by ammonia SCR,” Industrial & Engineering Chemistry Research, vol. 41, pp. 3512–3517, 2002.
View at: Google Scholar
G. Madia, M. Elsener, M. Koebel, F. Raimondi, and A. Wokaun, “Thermal stability of vanadia tungsta-titania catalysts in the SCR process,” Applied Catalysis B: Environmental, vol. 39, pp. 181–190, 2002.
View at: Google Scholar
P. Glarborg, J. A. Miller, B. Ruscic, and S. J. Klippenstein, “Modeling nitrogen chemistry in combustion,” Progress in Energy and Combustion Science, vol. 67, pp. 31–68, 2018.
View at: Google Scholar
Y. Song, H. Hashemi, J. M. Christensen, C. Zou, P. Marshall, and P. Glarborg, “Ammonia oxidation at high pressure and intermediate temperatures,” Fuel, vol. 181, pp. 358–365, 2016.
View at: Google Scholar
M. H. Kim and S. W. Park, “Selective reduction of NO by NH₃ over Fe-zeolite-promoted V₂O₅-WO₃/TiO₂-based catalysts: great suppression of N₂O formation and origin of NO removal activity loss,” Catalysis Communications, vol. 86, pp. 82–85, 2016.
View at: Google Scholar
M. H. Kim and H. S. Lee, “Effect of Fe-zeolite on formation of N₂O in selective reduction of NO by NH₃ over V₂O₅–WO₃/TiO₂ catalyst,” Research on Chemical Intermediates, vol. 42, no. 1, pp. 171–184, 2015.
View at: Google Scholar
W. Wang, R. Guo, W. Pan, and G. Hu, “Low temperature catalytic oxidation of NO over different-shaped CeO₂,” Journal of Rare Earths, vol. 36, pp. 588–593, 2018.
View at: Google Scholar
Z. Zhang, J. D. Atkinson, B. Jiang, M. J. Rood, and Z. Yan, “Nitric oxide oxidation catalyzed by microporous activated carbon fiber cloth: an updated reaction mechanism,” Applied Catalysis B: Environmental, vol. 148-149, pp. 573–581, 2014.
View at: Google Scholar
H. Wang, H. Chen, Y. Wang, and Y.-K. Lyu, “Performance and mechanism comparison of manganese oxides at different valence states for catalytic oxidation of NO,” Chemical Engineering Journal, vol. 361, pp. 1161–1172, 2019.
View at: Google Scholar
S. Cui, R. Hao, and D. Fu, “Integrated method of non-thermal plasma combined with catalytical oxidation for simultaneous removal of SO₂ and NO,” Fuel, vol. 246, pp. 365–374, 2019.
View at: Google Scholar
H. Yuan, J. Chen, H. Wang, and P. Hu, “Activity trend for low-concentration NO oxidation at room temperature on rutile-type metal oxides,” ACS Catalysis, vol. 8, pp. 10864–10870, 2018.
View at: Google Scholar
H. Yuan, J. Chen, Y. Guo, H. Wang, and P. Hu, “Insight into the superior catalytic activity of MnO₂ for low-content NO oxidation at room temperature,” The Journal of Physical Chemistry C, vol. 122, pp. 25365–25373, 2018.
View at: Google Scholar
X. Yao, J. Liu, and W. Wang, “Influence of B-site transition metal on NO oxidation over LaBO₃ (B=Mn, Fe and Co) perovskite catalysts,” AIP Advances, vol. 8, p. 115222, 2018.
View at: Google Scholar
S. Thampy, Y. Zheng, S. Dillon et al., “Superior catalytic performance of Mn-mullite over Mn-perovskite for NO oxidation,” Catalysis Today, vol. 310, pp. 195–201, 2018.
View at: Publisher Site | Google Scholar
Y. Song and L. C. Grabow, “Activity trends for catalytic CO and NO co-oxidation at low temperature diesel emission conditions,” Industrial & Engineering Chemistry Research, vol. 57, pp. 12715–12725, 2018.
View at: Google Scholar
C. Shi, H. Chang, C. Wang et al., “Improved activity and H₂O resistance of Cu-modified MnO2Catalysts for NO oxidation,” Industrial & Engineering Chemistry Research, vol. 57, no. 3, pp. 920–926, 2018.
View at: Publisher Site | Google Scholar
H. Chen, Y. Wang, and Y.-K. Lyu, “High catalytic activity of Mn-based catalyst in NO oxidation at low temperature and over a wide temperature span,” Molecular Catalysis, vol. 454, pp. 21–29, 2018.
View at: Google Scholar
Z. An, Y. Zhuo, C. Xu, and C. Chen, “Influence of the TiO₂ crystalline phase of MnO_x/TiO₂ catalysts for NO oxidation,” Chinese Journal of Catalysis, vol. 35, no. 1, pp. 120–126, 2014.
View at: Google Scholar
P. S. Metkar, V. Balakotaiah, and M. P. Harold, “Experimental and kinetic modeling study of NO oxidation: comparison of Fe and Cu-zeolite catalysts,” Catalysis Today, vol. 184, pp. 115–128, 2012.
View at: Google Scholar
Z. Wu, N. Tang, L. Xiao, Y. Liu, and H. Wang, “MnO(_x)/TiO(₂) composite nanoxides synthesized by deposition-precipitation method as a superior catalyst for NO oxidation,” Journal of Colloid and Interface Science, vol. 352, no. 1, pp. 143–148, 2010.
View at: Google Scholar
B.-Z. Sun, X.-L. Xu, W.-K. Chen, and L.-H. Dong, “Theoretical insights into the reaction mechanisms of NO oxidation catalyzed by Cu₂O(1 1 1),” Applied Surface Science, vol. 316, pp. 416–423, 2014.
View at: Google Scholar
Z. Wang, F. Lin, S. Jiang et al., “Ceria substrate-oxide composites as catalyst for highly efficient catalytic oxidation of NO by O₂,” Fuel, vol. 166, pp. 352–360, 2016.
View at: Publisher Site | Google Scholar
B.-L. Wang, J. Zhang, and H.-X. Zhong, “Effect of Ce doping content on catalytic performance of supported Co/ZrO₂ catalysts for combustion of methane,” Modern Chemical Industry, vol. 40, no. 12, pp. 151–155, 2020.
View at: Google Scholar
X.-H. Li, S.-L. Zhang, Y. Jia, X. Liu, and Q. Zhong, “Selective catalytic oxidation of NO with O₂ over Ce- doped MnO _{_x_} /TiO₂ catalysts,” Journal of Natural Gas Chemistry, vol. 21, no. 1, pp. 17–24, 2012.
View at: Publisher Site | Google Scholar
J. Zhou, L. Yu, M. Sun et al., “MnO₂ nanosheet-assisted hydrothermal synthesis of β-MnO₂ branchy structures,” Materials Letters, vol. 79, pp. 288–291, 2012.
View at: Publisher Site | Google Scholar
L. Qiu, J.-J. Meng, and D.-D. Pang, “Reaction and characterization of Co and Ce doped Mn/TiO₂ catalysts for low-temperature SCR of NO with NH₃,” Catalysis Letters, vol. 145, no. 7, pp. 1500–1509, 2015.
View at: Google Scholar
I. Atribak, A. Bueno-López, A. García-García, P. Navarro, D. Frías, and M. Montes, “Catalytic activity for soot combustion of birnessite and cryptomelane,” Applied Catalysis B: Environmental, vol. 93, no. 3-4, pp. 267–273, 2010.
View at: Google Scholar
Z. Wu, R. Jin, Y. Liu, and H. Wang, “Ceria modified MnO_x/TiO₂ as a superior catalyst for NO reduction with NH₃ at low-temperature,” Catalysis Communications, vol. 9, no. 13, pp. 2217–2220, 2008.
View at: Google Scholar
J. Xiang, L.-L. Wang, F. Cao et al., “Adsorption properties of NO and NH₃ over MnO_x based catalyst supported on γ-Al₂O₃,” Chemical Engineering Journal, vol. 302, pp. 570–576, 2016.
View at: Publisher Site | Google Scholar
M. Lykaki, E. Pachatouridou, S. A. C. Carabineiro et al., “Ceria nanoparticles shape effects on the structural defects and surface chemistry: implications in CO oxidation by Cu/CeO₂ catalysts,” Applied Catalysis B: Environmental, vol. 230, pp. 18–28, 2018.
View at: Publisher Site | Google Scholar
Y. Cui and W.-L. Dai, “Support morphology and crystal plane effect of Cu/CeO2nanomaterial on the physicochemical and catalytic properties for carbonate hydrogenation,” Catalysis Science & Technology, vol. 6, no. 21, pp. 7752–7762, 2016.
View at: Publisher Site | Google Scholar
X.-L. Guo and R.-X. Zhou, “A new insight into the morphology effect of ceria on CuO/CeO₂ catalysts for CO selective oxidation in hydrogen-rich gas,” Catalysis Science & Technology, vol. 6, pp. 3862–3871, 2016.
View at: Google Scholar
C. Wang, Q.-P. Cheng, X.-L. Wang et al., “Enhanced catalytic performance for CO preferential oxidation over CuO catalysts supported on highly defective CeO₂ nanocrystals,” Applied Surface Science, vol. 422, no. 15, pp. 932–943, 2017.
View at: Publisher Site | Google Scholar
L. Jiang, Q. Liu, G. Ran et al., “V₂O₅-modified Mn-Ce/AC catalyst with high SO₂ tolerance for low-temperature NH₃-SCR of NO,” Chemical Engineering Journal, vol. 370, pp. 810–821, 2019.
View at: Google Scholar
K. Li, X. Tang, H. Yi, P. Ning, D. Kang, and C. Wang, “Low-temperature catalytic oxidation of NO over Mn-Co-Ce-Ox catalyst,” Chemical Engineering Journal, vol. 192, pp. 99–104, 2012.
View at: Google Scholar
H.-X. Jiang, J. Zhao, and D.-Y. Jiang, “Hollow MnO_x-CeO₂ nanospheres prepared by a green route: a novel low-temperature NH3-SCR catalyst,” Catalysis Letters, vol. 114, no. 2, article S0169433217316616, pp. 325–332, 2014.
View at: Google Scholar

Copyright

Copyright © 2021 Chunhui Mou et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

PDF Download Citation

Download other formats

Order printed copies