Research Article
Adsorptive Removal of Alizarin Red S onto Sulfuric Acid-Modified Avocado Seeds: Kinetics, Equilibrium, and Thermodynamic Studies
Table 5
Rate constants and other parameters for the adsorption kinetics.
| Models | Parameters | Values | 50 mg/L | 100 mg/L | 150 mg/L | 200 mg/L | 250 mg/L | qe, exp (mg/g) | 17.15 | 32.92 | 47.53 | 60.86 | 68.95 |
| PFO | k1 (min-1) | 0.1091 | 0.08358 | 0.0722 | 0.06646 | 0.06241 | qe, cal (mg/g) | 16.88 | 33.85 | 49.55 | 64.08 | 73.7 | R2 | 0.9845 | 0.9604 | 0.9434 | 0.9359 | 0.9275 | SSE | 0.4078 | 7.334 | 28.97 | 61.52 | 100.4 | RMSE | 0.3193 | 1.354 | 2.691 | 3.922 | 5.011 |
| PSO | k2 (g/mg.Min) | 0.00816 | 0.002414 | 0.001241 | 0.0008203 | 0.0006321 | qe, cal (mg/g) | 19.15 | 40.46 | 61.26 | 80.82 | 94.48 | R2 | 0.9063 | 0.8943 | 0.886 | 0.8843 | 0.8797 | SSE | 2.465 | 19.59 | 58.32 | 111 | 166.6 | RMSE | 0.785 | 2.213 | 3.818 | 5.269 | 6.454 |
| Intraparticle diffusion | kp (mg/(g.min(1/2)) | 1.127 | 3.0413 | 5.098 | 7.043 | 8.491 | C | 9.0173 | 12.133 | 12.584 | 12.511 | 11.036 | R2 | 0.6229 | 0.6512 | 0.668 | 0.683 | 0.69 |
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