Research Article

Adsorption of Cu(II) and Zn(II) onto Activated Carbon from Oil Palm Empty Fruit Bunch Prepared by Two-Step Acid Treatment and Microwave-Assisted Pyrolysis

Table 5

Isotherm parameters for the adsorption of Cu(II) and Zn(II) onto EFB and 2ACEFB.

Isotherm modelParametersAdsorbent-adsorbate
EFB-Cu2ACEFB-CuEFB-Zn2ACEFB-Zn

Two-parameter model
Langmuir


0.052
20.02
0.997
6.11
0.038
44.29
0.996
3.80
0.036
17.82
0.997
6.28
0.029
36.43
0.997
4.60
Freundlich


2.51
2.62
0.929
20.58
2.58
1.67
0.955
15.35
1.920
2.55
0.885
18.38
1.93
1.72
0.929
16.56
Temkin


315.97
0.604
0.984
11.27
350.21
0.403
0.972
18.65
697.39
0.825
0.937
75.52
757.95
0.527
0.964
48.41

Three-parameter model
Redlich-Peterson




1.009
0.049
1.000
0.977
2.985
6.05
1.938
0.066
0.9336
0.998
1.327
3.41
0.621
0.034
1.000
0.971
2.824
6.41
1.101
0.031
1.000
0.993
2.651
4.82
Sips model




MAPE
20.01
0.040
1.088
0.978
2.918
7.97
41.66
0.046
0.955
0.998
1.484
3.21
17.80
0.030
1.053
0.972
2.805
7.57
33.58
0.022
1.150
0.995
2.294
7.26
Toth model




M
20.28
0.053
0.987
0.976
3.016
6.02
40.67
0.045
0.987
0.997
1.555
2.41
18.06
0.034
1.000
0.971
2.82
6.41
36.00
0.031
1.000
0.993
2.66
4.82