Bioinorganic Chemistry and Applications

Research Article

In Search for Titanocene Complexes with Improved Cytotoxic Activity: Synthesis, X-Ray Structure, and Spectroscopic Study of Bis( -cyclopentadienyl)difluorotitanium(IV)

Table 2

Selected bond lengths (Å) and angles (°) for complex 1.
Ti-F( )1.853( )Ti-C( )2.363( )
Ti-F( )1.859( )Ti-C( )2.365( )
Ti-C( )2.375( )Ti-C( )2.396( )
Ti-C( )2.400( )Ti-Cp2.066
C( )-C( )1.358( )C( )-C( )1.386( )
C( )-C( )1.396( )C( )-C( )1.390( )
C( )-C( )1.411( )mean C-C1.388
F( )-Ti-F( )96.0( )F( )-Ti-Cp107.30
Cp-Ti- 128.53F( )-Ti-Cp106.46
C( )-C( )-C( )108.6( )C( )-C( )-C( )107.5( )
C( )-C( )-C( )106.8( )C( )-C( )-C( )109.2( )
C( )-C( )-C( )107.8( )Aver. C-C-C108.0
atoms are related to the unprimed ones by the symmetry operation x, y, 1/2-z.