Research Article
Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
Table 1
Crystallographic data and data collection parameters for [Cd(babb)2](pic)2.
| | Complex | [Cd(babb)2](pic)2 |
| | Molecular formula | C70H62CdN16O14 | | Molecular weight | 1463.76 | | Crystal system | Triclinic | | Space group | P-1 | | a (Å) | 13.903 (4) | | b (Å) | 14.146 (4) | | c (Å) | 19.330 (5) | | α (°) | 90.595 (3) | | β (°) | 110.890 (3) | | γ (°) | 106.325 (3) | | V (Å3) | 3382.5 (16) | | Z | 2 | | (mg m−3) | 1.437 | | F(000) | 1508 | | Crystal size (mm) | 0.40 × 0.38 × 0.30 | | θ range for data collection (°) | 2.25 to 25.00 | | h/k/l (max, min) | −16, 16/−15, 16/ −22, 22 | | Reflections collected | 20103 | | Independent reflections | 11730 [R(int) = 0.0253] | | Completeness to theta = 25.00 | 98.4% | | Refinement method | Full-matrix least-
squares on | | Data/restraints/parameters | 11730/49/910 | | Goodness-of-fit on | 1.008 | | Final R1, R2 indices [] | 0.0473, 0.1117 | | R1, wR2 indices (all data) | 0.0682, 0.1249 | | Largest differences peak and hole (e Å−3) | 0.986 and −0.537 |
|
|
