Research Article
Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine
Table 1
Crystal data and structure refinement parameters for the title complex.
| | Empirical formula | CuC10H12O6N2S | | Formula weight (g·mol−1) | 351.82 | | Temperature (K) | 296(2) | | Wavelength (Å) | 0.71073 | | Crystal system | Monoclinic | | Space group | C2/c | | a (Å) | 15.1279(7) | | b (Å) | 12.4488(6) | | c (Å) | 6.9987(3) | | β (°) | 105.9576(13) | | V (Å3) | 1267.23(10) | | Z | 4 | | Calculated density (g·cm−3) | 1.844 | | Absorption coefficient (mm−1) | 1.916 | | F(000) | 716 | | Crystal size (mm3) | 0.374 × 0.199 × 0.117 | | θ range for data collection (°) | 3.273–27.639 | | Index ranges | −19 ≤ h ≤ 19, −16 ≤ k ≤ 16, −9 ≤ l ≤ 8 | | Reflections collected/unique | 9535 | | Data/restraints/parameters | 1473/3/97 | | Goodness of fit on F2 | 0.974 | | Final R indices (I > 2σ (I)) | R1 = 0.0226, wR2 = 0.0579 | | R indices (all data) | R1 = 0.0238, wR2 = 0.0589 | | Largest differential peak and hole (e·Å−3) | 0.356 and −0.442 |
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