Synthesis, Characterization, Antimicrobial Properties, and Antioxidant Activities of Silver-N-Heterocyclic Carbene Complexes
Table 1
Physical and spectroscopic properties of silver-carbene complexes 3a-3j.
Compounds
Molecular formula
Isolated yield (%)
M.p (°C)
FT-IR ν(CN)(cm−1)
13C NMR Ag-C (carbene) (ppm)a
3a
C26H35AgClN3O
78
236-237
1442
Not observed
3b
C27H37AgClN3O
77
243-244
1443
Not observed
3c
C22H33AgBrN3O
34
227-228
1443
Not observed
3d
C20H29AgBrN3O
70
73-74
1446
Not observed
3e
C22H26AgCl2N3O
80
227-228
1441
Not observed
3f
C22H27AgClN3O
70
214-215
1440
Not observed
3g
C18H27AgClN3O2
67
114-115
1434
Not observed
3h
C19H29AgClN3O2
58
250-251
1444
Not observed
3i
C30H43AgBrN3O
62
177-178
1449
Not observed
3j
C26H35AgBrN3O
62
101-102
1446
Not observed
[a]Ag–C(carbene) bond resonance was not observed as a reason for the fluxional behavior of the Ag–NHCs [44]. Bold values represent the number of the synthesized compounds.
