Chinese Herbal Formula, Huayu Tongbi Fang, Attenuates Inflammatory Proliferation of Rat Synoviocytes Induced by IL-1β by Regulating Proliferation and Differentiation of T Lymphocytes

Table 1

Chemical components identified from HYTB by HPLC-ESI/MSⁿ.

Peak	Ionization mode	TR (min)	Formula	Identification	Peak area	Area (%)
1	+	1.46	C5H9NO2	Proline	1642000	1.8
2	−	1.73	C7H10O5	Shikimic acid	690900	1.3
3	+	1.79	C5H11NO2	L-Valine	76360	0.1
4	+	12.3	C23H28O11	Albiflorin	3810000	4.2
5	−	12.84	C26H28O14	Isoschaftoside	177500	0.3
6	+	12.93	C23H28O11	Paeoniflorin	4280000	4.7
7	−	13.27	C9H8O3	p-Coumaric acid	140300	0.3
8	+	14.21	C22H22O10	Calycosin-7-O-glucoside	2572000	2.8
9	+	15.21	C20H23NO4	Tetrahydrojatrorrhizine	7699000	8.4
10	+	16.24	C20H19NO5	Protopine	7553000	8.3
11	−	16.5	C7H6O3	4-Hydroxybenzoic acid	813700	1.5
12	−	16.88	C18H16O8	Rosmarinic acid	13000000	23.7
13	+	17.52	C20H20NO4	Jatrorrhizine	7553000	8.3
14	+	17.6	C20H18NO4	Epiberberine	5307000	5.8
15	+	17.71	C19H14NO4	Coptisine	11150000	12.2
16	+	18	C21H22O9	Liquiritin	906500	1.0
17	+	18.72	C22H27NO4	Corydaline	11150000	12.2
18	−	19.25	C26H22O10	Salvianolic acid A	2482000	4.5
19	+	19.95	C23H28O10	Isomucronulatol-7-O-glucoside	636600	1.2
20	+	20.88	C22H24NO4	Dehydrocorydaline	3605000	4.0
21	+	25.34	C16H12O4	Formononetin	2911000	3.2
22	+	33.75	C18H14O3	Dihydrotanshinone I	2155000	2.4
23	+	37.86	C19H20O3	Cryptotanshinone	5041000	5.5
24	+	37.89	C18H12O3	Tanshinone I	1663000	1.8
25	+	40.2	C19H18O3	IIA Tanshinone	5269000	5.8