Material Basis of the Difference between Hedysari Radix and Honey-Processed Hedysari Radix in Buzhong Yiqi

Table 5

Different compounds identified from aqueous extracts of HR and HPHR.

Number	Additive ion	m/z	Rt (s)	Chemical formula	Chemical compound	Content change	Classification
1	(M + CH3COO)-	401.1289	495.214	C12H22O11	Isomaltose	↑	Saccharides
2	M+	504.1686	266.273	C18H32O16	Maltotriose	↑	Saccharides
3	(M + CH3CN + H)+	192.0879	163.902	C5H10O5	D-xylose	↑	Saccharides
4	(2M + H)+	301.1060	34.252	C5H10O5	L-arabinose	↓	Saccharides
5	(M + NH4)+	360.1505	346.728	C12H22O11	Sucrose	↑	Saccharides
6	(M + H-H2O)+	163.0600	239.502	C6H12O6	D-Mannose	↑	Saccharides
7	(M + CH3CN + H)+	206.1020	128.180	C6H12O5	L-fucose	↑	Saccharides
8	M+	448.1064	373.428	C21H20O11	Astragalin	↓	Glycosides
9	(M-H2O-H)-	248.0783	93.979	C10H13N5O4	Adenosine	↓	Nucleoside
10	(M + H)+	417.1180	159.152	C21H20O9	Daidzin	↑	Isoflavone
11	(M + H)+	284.0921	184.435	C10H13N5O5	Guanosine	↑	Nucleoside
12	(2M-H)-	221.0808	55.663	C4H5N3O	Cytosine	↑	Nucleoside
13	(M-H)-	111.0206	84.037	C4H4N2O2	Uracil	↑	Nucleoside
14	M+	239.1486	58.902	C13H21NO3	Salbutamol	↑
15	(M + H-H2O)+	153.1274	153.176	C10H18O2	Oxidation linalool	↓	Ethers
16	M+	265.1120	317.969	C12H18Cl2N4OS	Thiamine	↓	Vitamin
17	(M-2H + 3Na)+	517.2392	381.388	C29H38O4	Celastrol	↑	Triterpenoids
18	(M + NH4)+	304.0875	191.723	C15H10O6	Luteolin	↑	Flavonoids
19	(M + H)+	285.0759	159.472	C16H12O5	Glycitein	↓	Isoflavone
20	(M + H)+	271.0602	39.835	C15H10O5	Apigenin	↓	Flavonoids
21	(M + H-H2O)+	100.0764	48.831	C5H11NO2	Betaine	↑	Alkaloids
22	(M + H)+	286.0801	37.186	C16H12O5	Calycosin	↑	Isoflavone
23	(M + H)+	553.1491	42.693	C22H22O10	Calycosin-7-O-beta-D-glucoside	↑	Isoflavone
24	(M + H)+	269.0807	186.693	C16H12O4	Formononetin	↑	Isoflavone

Note: indicates compared with the HR group, indicates compared with the HR group.