Research Article

Construction and Chemical Profile on “Activity Fingerprint” of Citri Reticulatae Pericarpium from Different Cultivars Based on HPLC-UV, LC/MS-IT-TOF, and Principal Component Analysis

Table 1

Similarity evaluation and contents of five compounds of CRP collected from different regions in China.

No.CultivarsSpecific originsHarvest timeStorage (years)SimilarityAverage similarityContents of five flavonoids (mg/g, n = 3)a,b
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S1C. reticulata “Chachi” from the Xinhui regionLuokeng, Xinhui, Guangdong2014.10.1640.9920.99432.24 ± 0.013.52 ± 0.000.34 ± 0.002.43 ± 0.000.26 ± 0.00
S2Yinhuwan, Xinhui, Guangdong2014.10.1440.99929.62 ± 0.023.72 ± 0.000.35 ± 0.002.39 ± 0.000.28 ± 0.00
S3Sanjiang, Xinhui, Guangdong2014.11.1840.99827.59 ± 0.053.27 ± 0.010.27 ± 0.002.14 ± 0.000.22 ± 0.00
S4Xiaogang, Xinhui, Guangdong2014.10.2440.99428.67 ± 0.014.31 ± 0.000.38 ± 0.002.82 ± 0.000.26 ± 0.00
S5Tianlu, Xinhui, Guangdong2014.11.2240.99538.15 ± 0.023.82 ± 0.000.39 ± 0.002.41 ± 0.000.28 ± 0.00
S6Yanan, Xinhui, Guangdong2014.10.0140.99338.51 ± 0.035.03 ± 0.000.44 ± 0.003.14 ± 0.000.47 ± 0.00
S7Siqian, Xinhui, Guangdong2014.11.2240.99626.72 ± 0.032.63 ± 0.000.18 ± 0.001.73 ± 0.000.21 ± 0.00
S8Shenlv, Xinhui, Guangdong2015.10.1130.99118.14 ± 0.002.84 ± 0.000.28 ± 0.001.76 ± 0.000.16 ± 0.00
S9Shuangshui, Xinhui, Guangdong2014.11.0240.99221.38 ± 0.013.56 ± 0.000.37 ± 0.002.18 ± 0.000.24 ± 0.00
S10Chakeng, Xinhui, Guangdong2014.11.2540.99730.27 ± 0.022.27 ± 0.000.19 ± 0.001.67 ± 0.000.19 ± 0.00
S11Nantan, Xinhui, Guangdong2014.10.2040.99130.10 ± 0.013.92 ± 0.000.22 ± 0.003.18 ± 0.000.25 ± 0.00
S12Qibao, Xinhui, Guangdong2014.11.1640.99324.33 ± 0.012.90 ± 0.000.26 ± 0.002.16 ± 0.000.28 ± 0.00

S13C. reticulata “Chachi” from other regionsKaiping, Jiangmen, Guangdong2014.09.2640.9740.97443.09 ± 0.034.45 ± 0.000.34 ± 0.003.10 ± 0.000.36 ± 0.00
S14Heshan, Jiangmen, Guangdong2014.11.1740.99133.75 ± 0.033.30 ± 0.000.28 ± 0.002.70 ± 0.000.30 ± 0.00
S15Gaoyao, Zhaoqing, Guangdong2014.10.2140.97528.56 ± 0.012.93 ± 0.000.22 ± 0.002.75 ± 0.000.27 ± 0.00
S16Gaoyao, Zhaoqing, Guangdong2014.11.2340.96857.51 ± 0.022.67 ± 0.000.18 ± 0.002.66 ± 0.000.30 ± 0.00
S17Wengyuanbazi, Shaoguan, Guangdong2014.11.2040.97134.69 ± 0.013.86 ± 0.000.30 ± 0.002.78 ± 0.000.35 ± 0.00
S18Longmen, Huizhou, Guangdong2014.10.1540.97739.32 ± 0.012.91 ± 0.000.31 ± 0.002.40 ± 0.000.31 ± 0.00
S19Longcheng, Huizhou, Guangdong2014.10.1840.97936.47 ± 0.003.65 ± 0.000.23 ± 0.002.93 ± 0.000.34 ± 0.00
S20Xinxing, Yunfu, Guangdong2014.11.0640.96929.42 ± 0.044.57 ± 0.010.39 ± 0.003.58 ± 0.010.45 ± 0.00
S21Cangwu, Wuzhou, Guangxi2014.10.1740.96336.33 ± 0.105.25 ± 0.010.33 ± 0.003.98 ± 0.010.36 ± 0.00
S22Lingshan, Qinzhou, Guangxi2014.11.1940.97541.14 ± 0.004.07 ± 0.000.26 ± 0.003.16 ± 0.000.41 ± 0.00

S23C. reticulata “Subcompressa”Huangyan, Taizhou, Zhejiang2014.12.1040.9240.88540.63 ± 0.002.77 ± 0.000.48 ± 0.002.15 ± 0.000.27 ± 0.00
S24Huangyan, Taizhou, Zhejiang2014.11.2040.84653.07 ± 0.022.07 ± 0.000.34 ± 0.001.86 ± 0.000.19 ± 0.00
S25C. reticulata “Wuyueju”Sihui, Zhaoqing, Guangdong2014.12.2440.9380.94124.98 ± 0.023.54 ± 0.000.07 ± 0.001.38 ± 0.000.14 ± 0.00
S26Deqing, Zhaoqing, Guangdong2014.12.2540.94133.49 ± 0.014.44 ± 0.000.06 ± 0.001.73 ± 0.000.22 ± 0.00
S27Sihui, Zhaoqing, Guangdong2014.12.2540.94333.13 ± 0.004.22 ± 0.000.06 ± 0.001.68 ± 0.000.18 ± 0.00

S28C. reticulata “Tankan”Chenghai, Shantou, Guangdong2015.02.1830.8730.87117.81 ± 0.014.19 ± 0.001.07 ± 0.000.68 ± 0.000.27 ± 0.00
S29Zhaoan, Zhangzhou, Fujian2015.02.2030.87621.91 ± 0.005.55 ± 0.001.38 ± 0.001.03 ± 0.000.32 ± 0.00
S30Puning, Jieyang, Guangdong2015.08.1530.86621.48 ± 0.015.13 ± 0.001.15 ± 0.000.84 ± 0.000.31 ± 0.00

S31C. reticulata “Biangan”Guiping, Guigang, Guangxi2014.12.2340.7650.76547.57 ± 0.001.76 ± 0.000.38 ± 0.000.69 ± 0.000.08 ± 0.00

S32C. reticulata “Nianju”Longmen, Huizhou, Guangdong2015.03.0130.9350.93552.46 ± 0.015.54 ± 0.000.05 ± 0.002.21 ± 0.000.46 ± 0.00

S33C. reticulata “Yichangju”Zhijiang, Yichang, Hubei2015.11.2630.4920.51853.29 ± 0.010.18 ± 0.000.66 ± 0.000.10 ± 0.000.05 ± 0.00
S34Honghu, Jingzhou, Hubei2014.12.0140.52556.59 ± 0.080.24 ± 0.000.47 ± 0.000.18 ± 0.000.05 ± 0.00
S35Yiling, Yichang, Hubei2014.10.2440.55676.49 ± 0.060.62 ± 0.000.39 ± 0.000.41 ± 0.000.06 ± 0.00
S36Yiling, Yichang, Hubei2014.10.2440.49370.20 ± 0.030.23 ± 0.000.55 ± 0.000.13 ± 0.000.05 ± 0.00
S37Dianjun, Yichang, Hubei2014.11.2740.52553.08 ± 0.020.26 ± 0.000.59 ± 0.000.10 ± 0.000.04 ± 0.00

S38C. reticulata “Dahongpao”Chuanshan, Suining, Sichuan2014.11.1640.9340.94054.25 ± 0.026.64 ± 0.000.15 ± 0.002.36 ± 0.000.46 ± 0.00
S39Shuangliu, Chengdu, Sichuan2014.12.3140.94943.91 ± 0.095.32 ± 0.010.07 ± 0.002.48 ± 0.000.43 ± 0.00
S40Fengjie, Chongqing, Sichuan2014.12.1740.92970.68 ± 0.036.16 ± 0.000.18 ± 0.002.72 ± 0.000.45 ± 0.00
S41Kai, Chongqing, Sichuan2015.11.2630.94849.76 ± 0.026.79 ± 0.000.07 ± 0.003.00 ± 0.000.52 ± 0.00
S42Anyue, Ziyang, Sichuan2015.11.2630.94045.40 ± 0.036.90 ± 0.010.22 ± 0.002.62 ± 0.000.51 ± 0.00

S43C. reticulata “Shiyueju”Gaoyao, Zhaoqing, Guangdong2014.12.2540.9580.96254.18 ± 0.025.55 ± 0.000.09 ± 0.004.29 ± 0.000.22 ± 0.00
S44Gaoyao, Zhaoqing, Guangdong2014.12.2440.96242.86 ± 0.045.45 ± 0.010.05 ± 0.004.36 ± 0.000.20 ± 0.00
S45Lipu, Guilin, Guangxi2014.12.2640.96343.54 ± 0.005.23 ± 0.000.05 ± 0.004.05 ± 0.000.16 ± 0.00
S46Guiping, Guigang, Guangxi2014.12.2440.95740.48 ± 0.014.12 ± 0.000.03 ± 0.003.50 ± 0.000.11 ± 0.00
S47Yingde, Qingyuan, Guangdong2014.12.2840.9650.18 ± 0.015.39 ± 0.000.10 ± 0.003.69 ± 0.000.20 ± 0.00
S48Yingde, Qingyuan, Guangdong2014.12.2540.96538.74 ± 0.004.77 ± 0.000.10 ± 0.003.68 ± 0.000.14 ± 0.00
S49Zengcheng, Guangzhou, Guangdong2014.12.2540.96740.40 ± 0.015.54 ± 0.000.11 ± 0.003.73 ± 0.000.21 ± 0.00

S50C. reticulata “Unshiu”Daxiang, Shaoyang, Hunan2014.10.2840.4730.55865.73 ± 0.060.07 ± 0.000.49 ± 0.000.06 ± 0.000.05 ± 0.00
S51Shigu, Hengyang, Hunan2014.10.3040.54061.06 ± 0.050.42 ± 0.000.60 ± 0.000.30 ± 0.000.08 ± 0.00
S52Zhangshu, Yichun, Jiangxi2014.10.2640.65756.94 ± 0.050.94 ± 0.000.47 ± 0.000.69 ± 0.000.19 ± 0.00
S53Lingui, Guilin, Guangxi2014.11.2840.56357.07 ± 0.010.40 ± 0.000.69 ± 0.000.19 ± 0.000.02 ± 0.00
S54C. reticulata “Xunwuju”Sanbiao, Xunwu, Jiangxi2014.11.0140.4850.48971.18 ± 0.010.18 ± 0.000.51 ± 0.000.14 ± 0.000.09 ± 0.00
S55Shuiyuan, Xunwu, Jiangx2014.11.0140.48061.02 ± 0.020.09 ± 0.000.36 ± 0.000.09 ± 0.000.05 ± 0.00
S56Luoshan, Xunwu, Jiangxi2014.11.0140.50164.51 ± 0.090.32 ± 0.000.92 ± 0.000.19 ± 0.000.06 ± 0.00

S57C. reticulata “Suavissima”Pingyang, Wenzhou, Zhejiang2014.11.0140.9450.94275.54 ± 0.039.48 ± 0.020.11 ± 0.007.35 ± 0.021.97 ± 0.01
S58Lucheng, Wenzhou, Zhejiang2014.12.2840.94250.53 ± 0.037.30 ± 0.000.10 ± 0.005.22 ± 0.011.33 ± 0.00
S59Ouhai, Wenzhou, Zhejiang2014.12.0140.93960.55 ± 0.027.25 ± 0.000.09 ± 0.005.84 ± 0.001.32 ± 0.00

S60C. reticulata “Qingjiangju”Qingjiang, Zixing, Hunan2014.11.3040.4850.50477.43 ± 0.040.02 ± 0.000.41 ± 0.000.05 ± 0.000.05 ± 0.00
S61Qingjiang, Zixing, Hunan2014.10.2840.50667.26 ± 0.040.14 ± 0.000.43 ± 0.000.09 ± 0.000.05 ± 0.00
S62Sishui, Zixing, Hunan2014.10.2840.52175.31 ± 0.030.27 ± 0.000.69 ± 0.000.14 ± 0.000.05 ± 0.00

S63C. reticulata “Tribute”Deqing, Zhaoqing, Guangdong2014.11.1640.9450.94948.52 ± 0.015.59 ± 0.000.46 ± 0.003.95 ± 0.001.18 ± 0.00
S64Deqing, Zhaoqing, Guangdong2014.11.0440.95343.90 ± 0.015.65 ± 0.000.45 ± 0.004.10 ± 0.001.15 ± 0.00
S65Deqing, Zhaoqing, Guangdong2014.11.3040.94926.97 ± 0.004.46 ± 0.000.35 ± 0.002.89 ± 0.000.88 ± 0.00

S66C. reticulata “Kinokuni”Nanfeng, Fuzhou, Jiangxi2014.10.2440.9510.95346.90 ± 0.016.02 ± 0.000.22 ± 0.003.22 ± 0.000.78 ± 0.00
S67Nanfeng, Fuzhou, Jiangxi2014.11.2040.95354.85 ± 0.019.29 ± 0.000.30 ± 0.005.06 ± 0.001.01 ± 0.00
S68Ningdu, Ganzhou, Jiangxi2014.11.2840.94551.61 ± 0.006.40 ± 0.000.19 ± 0.004.42 ± 0.000.73 ± 0.00
S69Nanfeng, Fuzhou, Jiangxi2014.10.2640.95646.97 ± 0.017.05 ± 0.000.20 ± 0.003.58 ± 0.000.66 ± 0.00
S70Ningdu, Ganzhou, Jiangxi2014.12.0340.96151.73 ± 0.016.40 ± 0.000.19 ± 0.004.44 ± 0.000.74 ± 0.00

S71C. reticulata “Erythrosa”Mengquan, Shimen, Hunan2014.10.2940.5710.53980.52 ± 0.100.62 ± 0.000.40 ± 0.000.33 ± 0.000.08 ± 0.00
S72Chujiang, Shimen, Hunan2014.10.2840.51265.63 ± 0.050.16 ± 0.000.36 ± 0.000.11 ± 0.000.05 ± 0.00
S73Zaoshi, Shimen, Hunan2014.10.2940.56747.05 ± 0.00.36 ± 0.000.77 ± 0.000.19 ± 0.000.05 ± 0.00
S74Xinguan, Shimen, Hunan2015.10.2130.50755.50 ± 0.030.11 ± 0.000.37 ± 0.000.08 ± 0.000.05 ± 0.00

S75C. reticulata “Bayueju”Dongbei, Lianzhou, Guangdong2014.11.2940.9410.94541.15 ± 0.026.53 ± 0.010.04 ± 0.005.28 ± 0.010.42 ± 0.00
S76Dongbei, Lianzhou, Guangdong2014.11.2340.94338.62 ± 0.014.99 ± 0.000.04 ± 0.004.33 ± 0.000.30 ± 0.00
S77Lipu, Guilin, Guangxi2014.10.2840.95041.50 ± 0.035.34 ± 0.000.16 ± 0.003.24 ± 0.000.35 ± 0.00
S78Sihui, Zhaoqing, Guangdong2014.10.2940.94746.37 ± 0.017.13 ± 0.000.08 ± 0.005.13 ± 0.000.46 ± 0.00

S79C. reticulata “Tangerina”Minhou, Fuzhou, Fujian2013.01.0850.9370.94345.35 ± 0.024.29 ± 0.000.06 ± 0.002.06 ± 0.000.34 ± 0.00
S80Fuqing, Fuzhou, Fujian2015.12.3030.94943.92 ± 0.026.69 ± 0.000.17 ± 0.003.17 ± 0.000.42 ± 0.00

S81C. reticulata “Yangshanju”Chenxi, Wuzhou, Guangxi2014.11.2040.9530.95043.44 ± 0.024.38 ± 0.000.10 ± 0.002.62 ± 0.000.30 ± 0.00
S82Yanan, Xinhui, Guangdong2014.10.2840.94642.16 ± 0.027.65 ± 0.000.35 ± 0.003.74 ± 0.000.47 ± 0.00

S83C. reticulata “Linhaiju”Yongquan, Linhai, Zhejiang2014.10.2740.4940.49970.18 ± 0.060.10 ± 0.000.40 ± 0.000.06 ± 0.000.05 ± 0.00
S84Yongquan, Linhai, Zhejiang2014.10.2940.50362.52 ± 0.070.07 ± 0.000.33 ± 0.000.07 ± 0.000.05 ± 0.00
S85C. reticulata “Ponkan”Pinghe, Zhangzhou, Fujian2015.02.2330.9460.95749.34 ± 0.046.05 ± 0.000.10 ± 0.004.46 ± 0.010.92 ± 0.00
S86Kecheng, Quzhou, Zhejiang2015.02.1730.96754.22 ± 0.016.70 ± 0.010.05 ± 0.004.19 ± 0.000.94 ± 0.00
S87Yongchun, Quanzhou, Fujian2015.02.1030.95949.07 ± 0.025.46 ± 0.000.04 ± 0.004.27 ± 0.000.90 ± 0.00
S88Dangyang, Yichang, Hubei2015.02.1530.95449.23 ± 0.015.41 ± 0.000.02 ± 0.003.65 ± 0.000.96 ± 0.00

a1–5 denote the components of hesperidin, nobiletin, 3,5,6,7,8,3′,4′-heptamethoxyflavone, tangeretin, and 5-hydroxy-6,7,8, 3′,4′-pentamethoxyflavone, respectively. bThe content values of five flavonoids are shown as mean ± standard deviation (SD).