Ecotypic Variations Affected the Biological Effectiveness of Thymus daenensis Celak Essential Oil

Table 2

Essential oil compositions for ecotypic Thymus daenensis (%).

Compounds	RI	RI [11]	TD1	TD2	TD3	TD4	TD5	TD6	TD7	TD8	TD9	TD10
α-Pinene	938	939		0.86	0.42	0.26				0.83	0.10
Camphene	953	954		0.14	0.08					0.36
β-Pinene	978	979		0.58						0.26	0.29
1-Octen-3-ol	980	979		0.08	0.23					0.18
β-Myrcene	990	991	0.81							0.70
α-Terpinene	1017	1017	0.06				0.46			2.80		0.75
p-Cymene	1025	1026	0.12	2.56	5.12	6.53		11.19	0.23	9.26	1.64	0.38
O-Cymene	1026	1027		5.19			8.05
δ-3-Carene	1029	1031		0.12
1,8-Cineole	1030	1032	0.10	1.76	2.76	1.08	0.40	0.92	0.18	1.73	0.13	0.21
Z-β-Ocimene	1037	1038	0.20
E-β-Ocimene	1047	1050							0.21		0.18
γ-Terpinene	1059	1060	0.03	0.44	1.78	0.66	1.40	1.68		3.91	0.26
Z-Linalool oxide	1074	1075	0.34
α-Terpinolene	1087	1089				0.13				0.41
Linalool	1098	1097	1.57	18.24	1.48	1.02	1.60	0.44	22.49	0.32	2.01	0.30
Z-β-Terpineol	1144	1144			0.16		0.60	0.24		0.59	0.12
Camphor	1148	1150		2.88	0.26				0.48	0.62
Menthone	1152	1153		2.22
Isopulegol	1150	1152		2.12
Isoborneol	1161	1162										0.62
Neomenthol	1167	1168		5.69
Borneol	1169	1170	2.85	1.99	2.44	3.99		1.44	1.64	4.04	0.69	0.01
Terpinen-4-ol	1175	1177	1.04	0.60	4.68	0.70		0.59	1.10	0.90
Isomenthol	1181	1183		3.00
α-Terpineol	1189	1190	1.92		0.58	1.62		0.58		2.28	14.01	0.61
Thymol methyl ether	1230	1235			0.22	0.12
Pulegone	1234	1237		17.57
Carvacrol methyl ether	1243	1245	3.14					1.90
Piperitone	1249	1253		1.97
Geraniol	1253	1254	2.02								14.84
Thymol	1303	1304	60.61	0.31	58.94	64.52	70.95	60.60	0.73	39.45	25.00	73.86
Carvacrol	1308	1310	7.45	20.90	14.86	5.14	8.82	6.22	51.89	16.29	26.12	7.89
δ-Elemene	1337	1339		0.08
Piperitenone	1340	1343		1.90
α-Terpinyl acetate	1347	1349	1.10			0.08						0.41
Thymol acetate	1354	1352								0.15
Eugenol	1358	1359	0.39									0.05
α-Copaene	1376	1377								0.24
Geranyl acetate	1381	1381	1.85				0.16		6.11		0.94
β-Bourbonene	1389	1388	0.14	0.44	0.04	0.04			0.12	0.12	0.14
β-Elemene	1390	1393		0.08
Z-Jasmone	1393	1395	0.14
Β-Caryophyllene	1420	1419	4.56	3.73	3.08	4.60	1.81	2.32	3.50	4.97	3.40	3.60
Aromadendrene	1440	1441	0.16					0.20		0.53
α-Himachalene	1451	1452				0.35
α-Humulene	1456	1455	0.24		0.12	0.17	0.10	0.11		0.24	1.15	0.20
γ-Muurolene	1480	1482	0.31		0.22		0.29	0.25		0.39		0.78
Germacrene D	1481	1485		0.21					0.75		0.20
Viridiflorene	1492	1497	0.46			0.26		0.47		0.62		0.51
α-Muurolene	1501	1500		0.28
α -Farnesene	1504	1506							0.34
β-Bisabolene	1507	1506	1.47		0.40	0.82	0.67	2.65	0.83	0.66	0.85	1.24
Cis-α-Bisabolene	1508	1507	0.66	0.26	0.23	3.82	0.11	1.68	0.20	1.33	2.68	4.61
γ-Cadinene	1515	1514	0.41	0.33	0.26		0.16	0.15	0.15	0.28
δ-Cadinene	1524	1523	0.41	0.28	0.52		0.31	0.44		0.59		0.66
Spathulenol	1579	1578	0.38	0.65		0.37		0.26	0.21	0.46	0.32	0.36
Caryophyllene oxide	1584	1583	0.27	0.41	0.38	1.84	0.71	0.84	0.93	2.00	1.69	1.56
Cubenol	1648	1646		0.10					0.52
α -Cadinol	1655	1656	0.08	0.72					3.58	0.06
α-Bisabolol	1687	1685								0.06		0.11
Others	—	—	4.71	1.31	0.74	1.88	3.40	4.83	2.81	2.37	3.24	1.28

Results are the average of two independent GC experiments. In order to reduce table complexity, the standard deviation values were ignored. RI represents the experimental retention index and RI donates the published retention index, extracted from Adams book [11].