Research Article
Quality Assessment of Licorice Based on Quantitative Analysis of Multicomponents by Single Marker Combined with HPLC Fingerprint
Table 6
The contents of eleven compounds in 21 batches of samples, as determined with the ESM and QAMS methods (µg/mL).
| No. | L10 | L1 | L2 | L3 | L4 | L5 | L6 | L7 | L8 | L9 | L11 | ESM | ESM | QAMS | ESM | QAMS | ESM | QAMS | ESM | QAMS | ESM | QAMS | ESM | QAMS | ESM | QAMS | ESM | QAMS | ESM | QAMS | ESM | QAMS |
| S1 | 6.3275 | 4.9282 | 4.7339 | 0.2500 | 0.2545 | 0.3364 | 0.3217 | 0.2750 | 0.3510 | 0.1140 | 0.1300 | 0.0159 | 0.0158 | 0.0101 | 0.0087 | 0.0319 | 0.0290 | 0.0350 | 0.0443 | 0.0473 | 0.0457 | S2 | 6.2125 | 5.4486 | 5.2322 | 0.5189 | 0.5279 | 0.9728 | 0.9746 | 0.1293 | 0.1634 | 0.0888 | 0.1023 | 0.3129 | 0.3425 | 0.0268 | 0.0254 | 0.0331 | 0.0303 | 0.0134 | 0.0164 | 0.0174 | 0.0135 | S3 | 3.8839 | 0.8822 | 0.8659 | 0.3655 | 0.3730 | 0.9823 | 0.9871 | 0.0745 | 0.0932 | 0.0580 | 0.0688 | 0.1320 | 0.1438 | 0.0691 | 0.0676 | 1.0445 | 1.1384 | 0.0071 | 0.0083 | 0.0170 | 0.0129 | S4 | 4.2390 | 1.1127 | 1.0864 | 0.4544 | 0.4633 | 0.375 | 0.3621 | 0.0914 | 0.1149 | 0.1371 | 0.1557 | 0.1708 | 0.1865 | 0.0505 | 0.0490 | 0.0817 | 0.0835 | 0.0585 | 0.0735 | 0.3029 | 0.3176 | S5 | 13.4997 | 8.7365 | 8.3572 | 1.2271 | 1.2451 | 2.0048 | 2.0285 | 0.3417 | 0.4359 | 0.1810 | 0.2031 | 0.2258 | 0.2460 | 0.0367 | 0.0352 | 0.0571 | 0.0564 | 0.0405 | 0.0515 | 0.0871 | 0.0897 | S6 | 6.6722 | 5.0856 | 4.8833 | 0.9787 | 0.9952 | 0.6499 | 0.6431 | 0.1078 | 0.1357 | 0.0427 | 0.0519 | 0.2133 | 0.2334 | 0.0110 | 0.0097 | 0.0201 | 0.0161 | 0.0495 | 0.0626 | 0.0379 | 0.0353 | S7 | 10.8709 | 7.3289 | 7.0174 | 1.3184 | 1.3383 | 1.5880 | 1.6027 | 0.0795 | 0.0992 | 0.0272 | 0.0350 | 0.1346 | 0.1473 | 0.0177 | 0.0164 | 0.0270 | 0.0237 | 0.0466 | 0.0588 | 0.0143 | 0.0098 | S8 | 4.8482 | 4.0770 | 3.9250 | 0.7425 | 0.7563 | 0.7022 | 0.6979 | 0.0280 | 0.0331 | 0.0422 | 0.0513 | 0.1819 | 0.1986 | 0.0231 | 0.0217 | 0.0357 | 0.0331 | 0.0064 | 0.0075 | 0.0206 | 0.0169 | S9 | 9.0135 | 1.6067 | 1.5545 | 2.2097 | 2.2442 | 1.5482 | 1.5628 | 0.0534 | 0.0656 | 0.0209 | 0.0279 | 0.1665 | 0.1812 | 0.0130 | 0.0116 | 0.0343 | 0.0315 | 0.2166 | 0.2759 | 0.0068 | 0.0021 | S10 | 4.8990 | 4.8665 | 4.6810 | 0.5400 | 0.5501 | 0.7249 | 0.7212 | 0.0806 | 0.1009 | 0.0280 | 0.0357 | 0.1937 | 0.2117 | 0.0374 | 0.036 | 0.0479 | 0.0465 | 0.0069 | 0.0081 | 0.0722 | 0.0721 | S11 | 9.5422 | 9.8666 | 9.4439 | 1.3883 | 1.4098 | 1.7495 | 1.7687 | 0.0208 | 0.0237 | 0.0149 | 0.0213 | 0.2073 | 0.2259 | 0.0145 | 0.0131 | 0.0435 | 0.0416 | 0.0034 | 0.0035 | 0.0273 | 0.0244 | S12 | 4.8746 | 4.1953 | 4.0382 | 0.6767 | 0.6892 | 0.7094 | 0.7053 | 0.0673 | 0.0837 | 0.0162 | 0.0229 | 0.1702 | 0.1863 | 0.0312 | 0.0299 | 0.0475 | 0.0462 | 0.0027 | 0.0027 | 0.0123 | 0.0079 | S13 | 3.6479 | 1.6691 | 1.6215 | 0.7561 | 0.7716 | 0.5910 | 0.5848 | 0.1540 | 0.1959 | 0.0282 | 0.0360 | 0.1943 | 0.2127 | 0.0405 | 0.0392 | 0.1377 | 0.1450 | 0.0071 | 0.0083 | 0.0144 | 0.0101 | S14 | 4.4932 | 2.9709 | 2.8668 | 0.8595 | 0.8758 | 0.7746 | 0.7727 | 0.0652 | 0.0811 | 0.0485 | 0.0584 | 0.1616 | 0.1767 | 0.0182 | 0.0168 | 0.0112 | 0.0063 | 0.0170 | 0.0210 | 0.0442 | 0.0417 | S15 | 6.3990 | 4.9279 | 4.7334 | 1.0538 | 1.0717 | 0.9740 | 0.9758 | 0.1645 | 0.2087 | 0.0242 | 0.0315 | 0.1639 | 0.1787 | 0.0083 | 0.007 | 0.0193 | 0.0152 | 0.1188 | 0.1512 | 0.0273 | 0.0241 | S16 | 2.8851 | 1.9474 | 1.8925 | 0.2062 | 0.211 | 0.4817 | 0.4733 | 0.0051 | 0.0036 | 0.0148 | 0.0213 | 0.1557 | 0.1704 | 0.0352 | 0.0339 | 0.0481 | 0.0469 | 0.0025 | 0.0024 | 0.0095 | 0.0049 | S17 | 2.4714 | 1.2900 | 1.2623 | 0.2627 | 0.2692 | 0.3730 | 0.3618 | 0.0603 | 0.0752 | 0.0130 | 0.0194 | 0.1121 | 0.1225 | 0.0219 | 0.0207 | 0.1542 | 0.1637 | 0.0740 | 0.0935 | 0.0131 | 0.0086 | S18 | 5.8168 | 2.7369 | 2.6387 | 1.0277 | 1.0457 | 0.3224 | 0.3075 | 0.0870 | 0.1090 | 0.0865 | 0.0999 | 0.1615 | 0.1760 | 0.0722 | 0.0706 | 0.1963 | 0.2086 | 0.0295 | 0.0371 | 0.0515 | 0.0501 | S19 | 2.5555 | 1.0776 | 1.0573 | 0.2175 | 0.2229 | 0.3891 | 0.3783 | 0.0727 | 0.0912 | 0.0439 | 0.0534 | 0.1499 | 0.1643 | 0.0665 | 0.0653 | 0.0228 | 0.0191 | 0.0060 | 0.0068 | 0.0384 | 0.0349 | S20 | 4.6090 | 3.5481 | 3.4194 | 0.3558 | 0.3627 | 0.5149 | 0.5057 | 0.0277 | 0.0327 | 0.0126 | 0.0188 | 0.2404 | 0.2632 | 0.0657 | 0.0642 | 0.0389 | 0.0367 | 0.0026 | 0.0026 | 0.0143 | 0.0101 | S21 | 5.1993 | 2.3993 | 2.3170 | 0.8755 | 0.8914 | 0.238 | 0.2209 | 0.0732 | 0.0913 | 0.0538 | 0.0640 | 0.1363 | 0.1483 | 0.0623 | 0.0608 | 0.1765 | 0.1871 | 0.0276 | 0.0346 | 0.0233 | 0.0198 | Mean | 5.8553 | 3.8430 | 3.6966 | 0.7755 | 0.7890 | 0.8096 | 0.8075 | 0.0980 | 0.1233 | 0.0522 | 0.0623 | 0.1715 | 0.1872 | 0.0349 | 0.0335 | 0.1100 | 0.1145 | 0.0367 | 0.0462 | 0.0428 | 0.0406 | Cir | | 0.9998 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | r | | 0.9999 | 0.9997 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 | 0.9999 |
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