Research Article
Simultaneous Determination of 25 Ginsenosides by UPLC-HRMS via Quantitative Analysis of Multicomponents by Single Marker
Table 4
Relative response factor (RCF) and relative standard deviation (RSD) values of 25 ginsenosides.
| | Ginsenoside | Concentration (ng/mL) | Mean | RSD (%) | | 10 | 20 | 50 | 100 | 200 |
| | Rb2 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | ā | ā | | Rg1 | 0.32 | 0.30 | 0.31 | 0.30 | 0.30 | 0.31 | 2.92 | | Re | 0.48 | 0.46 | 0.47 | 0.48 | 0.46 | 0.47 | 2.13 | | Rf | 0.48 | 0.48 | 0.52 | 0.48 | 0.50 | 0.49 | 3.64 | | Rb1 | 3.45 | 3.25 | 3.05 | 3.18 | 3.22 | 3.23 | 4.48 | | Rg2 | 0.44 | 0.43 | 0.46 | 0.42 | 0.42 | 0.43 | 3.86 | | Rh1 | 0.09 | 0.09 | 0.09 | 0.09 | 0.08 | 0.09 | 5.08 | | Rc | 0.93 | 0.88 | 0.94 | 0.94 | 0.92 | 0.92 | 2.70 | | F1 | 0.07 | 0.08 | 0.08 | 0.08 | 0.08 | 0.08 | 2.83 | | Rb3 | 0.97 | 0.97 | 0.98 | 0.99 | 0.98 | 0.98 | 0.86 | | Rd | 0.36 | 0.34 | 0.35 | 0.34 | 0.34 | 0.35 | 2.59 | | GXVII | 0.24 | 0.24 | 0.25 | 0.23 | 0.24 | 0.24 | 2.95 | | nFe | 0.62 | 0.67 | 0.66 | 0.69 | 0.68 | 0.66 | 4.07 | | CO | 0.60 | 0.62 | 0.63 | 0.66 | 0.65 | 0.63 | 3.78 | | nFd | 1.05 | 1.00 | 1.05 | 0.99 | 1.05 | 1.03 | 2.95 | | F2 | 0.10 | 0.10 | 0.09 | 0.10 | 0.10 | 0.10 | 4.56 | | G75 | 0.09 | 0.09 | 0.09 | 0.08 | 0.09 | 0.09 | 5.08 | | Rg3 | 0.14 | 0.14 | 0.14 | 0.13 | 0.14 | 0.14 | 3.24 | | PPT | 1.00 | 0.97 | 0.95 | 0.99 | 1.01 | 0.98 | 2.45 | | Mc | 0.33 | 0.34 | 0.34 | 0.36 | 0.34 | 0.34 | 3.20 | | CY | 0.47 | 0.48 | 0.50 | 0.49 | 0.47 | 0.48 | 2.71 | | CMx | 0.24 | 0.25 | 0.25 | 0.26 | 0.25 | 0.25 | 2.83 | | CK | 0.14 | 0.13 | 0.14 | 0.15 | 0.14 | 0.14 | 5.05 | | Rh2 | 0.06 | 0.07 | 0.07 | 0.07 | 0.07 | 0.07 | 3.24 | | PPD | 6.48 | 6.95 | 6.67 | 6.98 | 6.45 | 6.71 | 3.75 |
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