Analytical Steady-State Model for the Free Radical Solution Copolymerization of Acrylonitrile and Vinyl Acetate and Their Charge-Transfer Complex in a Continuous Stirred Tank Reactor

Table 2

Kinetic parameters used for reactor modeling.

[14]	initiator efficiency [14]
[14]	°C
Monomer 1 (AN) [14]
Monomer 2 (VA) [15]
Copolymerization [16]

E_p22: propagation energy of monomer 2, E_t22: termination energy of monomer 2, E_p12: propagation energy of growing radical P with monomer 2, E_p21: propagation energy of growing radical Q with monomer 1, k_p11: propagation monomer 1 rate constant, k_p12: propagation growing radical P with monomer 2 rate constant, r1: copolymerization reactivity ratio 1.