Research Article

Ultrahigh Performance Piezoelectric Energy Harvester Using Lead-Free Piezoceramics with Large Electromechanical Coupling Factor

Table 2

Various parameters of the textured KN(N1-zSz)-BAZ-SZ piezoelectric ceramics () obtained from the Rietveld refinement.

SbPhase structurePhase fraction (%)Lattice parameters (%) (%)
a ()b ()c (), ,

0.00O-T90.7 (Amm2)3.9621 (3)5.6545 (4)5.6589 (4)°4.706.154.07
9.3(P4mm)3.9751 (3)3.9751 (3)3.9764 (3)°

0.01R-O-T4.8 (R3m; H)5.6635 (9)5.6635 (9)6.9955 (24)°, °3.844.862.39
82.6 (Amm2)3.9655 (3)5.6503 (4)5.6535 (4)°
12.6 (P4mm)3.9725 (3)3.9725 (3)3.9819 (3)°

0.03R-O-T20.8 (R3m; H)5.6285 (5)5.6285 (5)6.9084 (12)°, °4.446.274.30
62.0 (Amm2)3.9620 (3)5.6393 (4)5.6425 (4)°
17.2 (P4mm)3.9699 (4)3.9699 (4)3.9793 (4)°

0.05R-O-T30.5 (R3m; H)5.6250 (3)5.6250 (3)6.8997 (7)°, °4.305.903.76
45.1 (Amm2)3.9649 (3)5.6384 (4)5.6416 (4)°
24.4 (P4mm)3.9717 (3)3.9717 (3)3.9812 (3)°

0.06R-O-T33.2 (R3m; H)5.6254 (2)5.6254 (2)6.9005 (5)°, °4.215.673.78
34.1 (Amm2)3.9695 (3)5.6395 (3)5.6427 (3)°
32.7 (P4mm)3.9747 (2)3.9747 (2)3.9841 (2)°

0.08R-O-T38.9 (R3m; H)5.62450 (1)5.6250 (1)6.8996 (3)°, °4.295.874.23
15.9 (Amm2)3.9690 (3)5.6374 (3)5.6405 (3)
45.2 (P4mm)3.9756 (1)3.9756 (1)3.9850 (1)°