Research Article
Prepolymerization of Lacquer Sap under Pure Oxygen Atmosphere and Its Effects on the Properties of Lacquer Film
Table 1
The molecular weight distribution of the raw and the prepolymerized lacquer saps under different atmospheres.
| Sample | Prepolymerization time | Oxygen atmosphereb | Air atmosphere | Polymer/% | Oligomer/% | Monomer/% | Polymer/% | Oligomer/% | Monomer/% |
| RLa | 0 h | 0.09 | 17.23 | 82.68 | 0.09 | 17.23 | 82.68 | 1 | 0.5 h | 3.64 | 48.61 | 47.75 | 0.50 | 28.29 | 71.21 | 2 | 1.0 h | 4.66 | 58.32 | 37.02 | 0.63 | 31.44 | 67.93 | 3 | 1.5 h | 7.10 | 55.35 | 37.55 | 0.88 | 32.87 | 66.25 | 4 | 2.0 h | 10.95 | 58.62 | 30.43 | 1.08 | 33.34 | 65.58 | 5 | 2.5 h | 15.84 | 54.38 | 29.78 | 1.10 | 34.17 | 64.73 | 6 | 3.0 h | 20.48 | 56.24 | 23.28 | 1.51 | 37.85 | 60.64 |
|
|
Raw lacquer; bpolymer: ; oligomer: ; monomer: .
|