Effects of Ultrasound Technique on the Composition of Different Essential Oils

Table 6

Changes in the chemical composition in solutions of hyssop oil.

Compound	IR	Chemical composition of essential oil (mg/ml)
		Alcohol solutions					Hexane solutions
		A	B	C	D	K	A	B	C	D	K
Thujene <alpha->	931	0.39	0.38	0.39	0.41	0.41	0.41	0.43	0.42	0.44	0.43
Pinene <alpha->	939	1.26	1.25	1.26	1.34	1.33	1.33	1.41	1.38	1.43	1.39
Sabinene	975	2.30	2.26	2.26	2.39	2.33	2.32	2.43	2.41	2.48	2.40
Pinene <beta->	939	13.78^a	13.96^a	13.73^a	13.32^a	13.93^a	13.62^a	13.15^a	13.29^a	12.51^a	13.00^a
Myrcene	994	2.39	2.35	2.40	2.55	2.46	2.44	2.52	2.52	2.58	2.55
Limonene	1030	1.77	1.71	1.72	1.77	1.72	1.75	1.79	1.78	1.75	1.73
Cineole <1,8->	1033	6.23^a	6.13^a	5.89^a	5.75^a	5.60^a	5.62^a	5.76^a	5.74^a	5.78^a	5.55^a
Ocimene <(Z)-beta->	1037	1.01	1.00	1.02	1.08	1.05	1.05	1.09	1.07	1.11	1.10
Terpinene <gamma->	1060	0.20	0.20	0.21	0.22	0.21	0.21	0.22	0.22	0.22	0.23
Linalool	1099	1.42	1.37	1.48	1.57	1.50	1.53	1.64	1.55	1.69	1.72
Thujone <cis->	1105	0.20	0.20	0.22	0.12	0.22	0.23	0.26	0.23	0.26	0.27
Thujone <trans->	1116	0.18	0.17	0.18	0.19	0.18	0.19	0.21	0.19	0.21	0.21
Pinocarveol <trans->	1138	0.42	0.41	0.43	0.46	0.45	0.47	0.44	0.48	0.46	0.46
Pinocarvone	1163	8.20^a	8.68^a	8.30^a	7.85^a	7.98^a	8.00^a	8.21^a	8.13^a	8.26^a	7.75^a
Pinocamphone <cis->	1174	28.52^a	29.38^a	28.98^a	27.85^a	28.34^a	28.49^a	27.17^a	28.03^a	27.92^a	27.28^a
Pinocamphone <trans-2-hydroxy->	1249	0.18	0.17	0.18	0.19	0.19	0.21	0.21	0.21	0.22	0.24
Bourbonene <beta->	1390	1.74	1.67	1.71	1.83	1.78	1.77	1.79	1.78	1.83	1.90
Methyl eugenol	1405	0.31	0.30	0.32	0.35	0.35	0.36	0.37	0.36	0.38	0.39
Gurjunene <alpha->	1412	0.62	0.60	0.61	0.68	0.66	0.65	0.67	0.66	0.69	0.72
Caryophyllene <E->	1420	1.37	1.32	1.31	1.34	1.43	1.41	1.44	1.42	1.47	1.53
Humulene <alpha->	1455	0.28	0.27	0.28	0.30	0.30	0.29	0.30	0.29	0.31	0.32
Aromadendrene <allo->	1461	1.99	1.93	1.95	2.07	2.02	1.98	2.03	1.99	2.06	2.10
Germacrene D	1487	3.00	2.87	2.91	3.06	2.96	2.95	2.96	2.94	2.88	3.02
Bicyclogermacrene	1503	3.18	3.07	3.04	3.16	3.06	3.06	3.07	3.06	3.09	3.20
Cadinene <gamma->	1515	0.46	0.45	0.46	0.50	0.50	0.49	0.50	0.48	0.26	0.53
Elemol	1550	1.73	1.69	1.69	1.85	1.81	1.87	1.93	1.86	1.77	2.00
Spathulenol	1579	0.88	0.86	0.90	0.98	0.96	0.97	1.00	0.97	0.97	1.06
Caryophyllene oxide	1585	0.34	0.33	0.35	0.38	0.38	0.37	0.39	0.38	0.36	0.42
Viridiflorol	1594	0.28	0.27	0.28	0.33	0.32	0.33	0.34	0.33	0.32	0.37
Cadinol <epi-alpha->	1640	0.38	0.37	0.41	0.45	0.45	0.48	0.49	0.48	0.48	0.55
Eudesmol <alpha->	1654	0.46	0.45	0.49	0.55	0.55	0.54	0.56	0.53	0.55	0.60

Designation according to Table 1. IR: retention indices (from temperature programming, using the definition of Van den Dool and Kratz [17]). Values designated with the same superscript letters for the dominant compound do not significantly differ at 5% error (Duncan’s test).