Simultaneous Determination of Eight Chemical Components in Angelicae Sinensis Radix and Its Herbal Products by QAMS
Table 4
Content of 8 components in 10 batches of ASR and its 12 kinds of preparations determined by QAMS and ESM (mg/g).
Sample/PD
Chlorogenic acid
Ferulic acid
Senkyunolide I
Senkyunolide H
Coniferyl ferulate
Senkyunolide A
ligustilide
Levistolide A
ESM
QAMS
ESM
ESM
QAMS
ESM
QAMS
ESM
QAMS
ESM
QAMS
ESM
QAMS
ESM
QAMS
S1
1.453
1.512
1.446
0.262
0.256
0.073
0.072
0.618
0.63
0.108
0.106
17.703
17.522
0.337
0.347
PD (%)
3.980
−2.317
−1.379
1.923
−1.869
−1.0277
2.924
S2
0.273
0.284
0.836
1.029
1.006
0.27
0.265
1.316
1.34
0.107
0.104
7.898
7.817
0.538
0.555
PD (%)
3.950
−2.260
−1.869
1.807
−2.845
−1.031
3.111
S3
0.339
0.353
0.592
0.674
0.659
0.161
0.158
2.429
2.473
0.178
0.174
13.201
13.065
0.355
0.366
PD (%)
4.046
−2.251
−1.881
1.795
−2.273
−1.036
3.051
S4
0.387
0.402
0.670
0.937
0.916
0.247
0.242
1.110
1.130
0.212
0.208
7.194
7.12
0.452
0.465
PD (%)
3.802
−2.267
−2.045
1.786
−1.905
−1.034
2.835
S5
0.387
0.402
0.762
0.302
0.296
0.088
0.086
4.079
4.153
0.242
0.237
26.496
26.224
1.039
1.071
PD (%)
3.802
−2.007
−2.299
1.798
−2.087
−1.032
3.033
S6
1.94
2.019
1.008
0.152
0.149
0.041
0.04
1.597
1.626
0.136
0.134
17.816
17.633
0.414
0.426
PD (%)
3.991
−1.993
−2.469
1.800
−1.481
−1.032
2.857
S7
0.619
0.644
0.965
0.359
0.351
0.112
0.11
0.857
0.872
0.127
0.124
12.469
12.341
0.437
0.45
PD (%)
3.959
−2.253
−1.802
1.735
−2.390
−1.032
2.931
S8
0.464
0.483
0.932
0.542
0.53
0.214
0.21
0.959
0.976
0.131
0.128
9.076
8.983
0.438
0.451
PD (%)
4.013
−2.239
−1.887
1.757
−2.317
−1.030
2.925
S9
0.816
0.849
0.88
0.625
0.611
0.094
0.092
1.236
1.258
0.159
0.156
10.584
10.475
0.335
0.345
PD (%)
3.964
−2.265
−2.151
1.764
−1.905
−1.035
2.941
S10
0.422
0.44
0.708
0.791
0.773
0.174
0.171
1.348
1.373
0.194
0.189
9.811
9.711
0.402
0.414
PD (%)
4.176
−2.302
−1.739
1.838
−2.611
−1.024
2.941
S11
0.615
0.64
0.436
0.433
0.423
0.115
0.113
0.063
0.064
0.094
0.092
6.731
6.662
0.406
0.418
PD (%)
3.984
−2.336
−1.754
1.575
−2.151
−1.030
2.913
S12
0.052
0.054
0.406
0.173
0.169
0.056
0.055
0.047
0.048
0.048
0.047
1.952
1.932
0.101
0.105
PD (%)
3.773
−2.339
−1.802
2.105
−2.105
−1.030
3.883
S13
0.159
0.165
0.242
0.211
0.206
0.061
0.059
0.060
0.061
0.306
0.299
0.737
0.730
0.069
0.071
PD (%)
3.704
−2.398
−3.333
1.653
−2.314
−0.954
2.857
S14
/
/
0.056
0.145
0.142
0.025
0.024
0.090
0.092
0.032
0.031
1.040
1.030
0.083
0.085
PD (%)
/
−2.091
−4.082
2.198
−3.175
−0.966
2.381
S15
0.327
0.341
0.487
0.1
0.098
0.03
0.029
0.047
0.048
0.037
0.036
1.348
1.334
0.061
0.063
PD (%)
4.192
−2.020
−3.390
2.105
−2.740
−1.044
3.226
S16
0.048
0.050
0.047
0.071
0.069
0.022
0.021
0.022
0.023
0.047
0.046
0.259
0.256
0.039
0.040
PD (%)
4.082
−2.857
−4.651
4.444
−2.151
−1.165
2.532
S17
0.04
0.042
0.414
0.131
0.128
0.039
0.038
0.038
0.039
0.162
0.158
0.714
0.707
0.048
0.050
PD (%)
4.878
−2.3167
−2.597
2.597
−2.500
−0.985
4.082
S18
0.45
0.469
0.586
0.156
0.152
0.068
0.067
0.110
0.112
0.081
0.079
0.618
0.612
0.058
0.060
PD (%)
4.135
−2.597
−1.481
1.802
−2.500
−0.976
3.390
S19
0.394
0.41
0.612
0.167
0.163
0.051
0.050
0.059
0.060
0.392
0.384
0.728
0.720
0.072
0.074
PD (%)
3.980
−2.424
−1.980
1.681
−2.062
−1.105
2.740
S20
1.375
1.431
5.568
0.299
0.292
0.347
0.341
1.692
1.722
1.005
0.983
1.457
1.442
0.036
0.037
PD (%)
3.991
−2.369
−1.744
1.757
−2.213
−1.035
2.740
S21
0.475
0.494
1.026
0.331
0.323
0.177
0.173
0.292
0.297
0.586
0.573
1.648
1.632
0.127
0.131
PD (%)
3.922
−2.446
−2.286
1.698
−2.243
−0.976
3.101
S22
0.463
0.482
0.611
0.267
0.261
0.087
0.086
0.425
0.432
0.260
0.255
2.069
2.048
0.120
0.123
PD (%)
4.021
−2.273
−1.156
1.634
−1.942
−1.020
2.469
Note. S1–S10 are 10 batches of ASR; S11 is concentrated Danggui pills; S12 is Danggui Kushen pills; S13 is Tiaojing Zhitong tablets; S14 is Danggui Futongning dropping pills; S15 is Xiaoyao pills; S16 is Wuji Baifeng pills; S17 is Bazhen Yimu pills; S18 is Bu-Zhong-Yi-Qi pills; S19 is Aifu Nuangong pills; S20 is Niuhuang Shangqing tablets; S21 is Yangxue Qingnao granules; and S22 is Fuke Tiaojing tablets.
