Hybrid Layered Crystal Comprising Polyoxometalate and Surfactant Synthesized from Reduced Mo-Blue Species

Table 2

C--H⋯O hydrogen bonds in C₁₆py-H₂Mo₈.

	C--H (Å)	H⋯O (Å)	C⋯O (Å)	C--H⋯O (deg)
Between 𝛽-H2Mo8 and C16py
C5^i--H5^i⋯O8	0.96(6)	2.84(6)	3.722(6)	152(5)
C6^i--H6B^i⋯O8	0.81(7)	2.92(7)	3.726(8)	175(6)
C17^ii--H17B^ii⋯O8	0.92(4)	2.75(4)	3.641(5)	165(4)
C2^iii--H2^iii⋯O9	0.89(5)	2.62(5)	3.450(7)	156(4)
C19^ii--H19B^ii⋯O9	0.97(3)	3.05(3)	3.993(5)	163(3)
C21^iv--H21B^iv⋯O12	0.95(5)	2.66(5)	3.536(6)	153(5)
Between 𝛽-H2Mo8 and ethanol
C22^v--H22A^v⋯O3	0.989(4)	2.139(2)	3.097(5)	162.5(2)

Symmetry codes: ⁱ−x, −𝑦, −𝑧; ⁱⁱ−1 + 𝑥, 𝑦, 𝑧; ⁱⁱⁱ−x, 1 − 𝑦, −𝑧; ^iv1−𝑥, −0.5 + 𝑦, −0.5−𝑧; ^v𝑥, 0.5−𝑦, −0.5 + 𝑧.