Syntheses, Crystal Structures, Magnetic Behaviours, and Thermal Properties of Three Hydrogen-Bonding Networks Containing Dicyanamide and 4-Hydroxypyridine

Table 2

The selected bond lengths [Å] and angles [°] for complexes 1–3.

1
Bonds
Mn(1)-N(1)	2.221(2)	Mn(1)-O(1)	2.2099(16)
Mn(1)-N(3b)	2.212(2)
Angles
O(1)-Mn(1)-N(1a)	93.72(8)	O(1)-Mn(1)-N(3b)	89.78(8)
N(3b)-Mn(1)-N(1a)	88.00(8)	O(1)-Mn(1)-N(1)	86.28(8)
N(3c)-Mn(1)-N(1a)	92.00(8)	O(1)-Mn(1)-N(3c)	90.22(8)
2
Bonds
Cd(1)-N(2a)	2.3066(16)	Cd(1)-N(4c)	2.3166(17)
Cd(1)-O(1)	2.3279(12)
Angles
N(2a)-Cd(1)-N(4)	88.38(6)	N(2a)-Cd(1)-O(1)	90.47(6)
N(2b)-Cd(1)-N(4)	91.62(6)	N(2b)-Cd(1)-O(1)	89.53(6)
N(4c)-Cd(1)-O(1)	95.34(6)	N(4)-Cd(1)-O(1)	84.66(6)
3
Bonds
Co(1)-O(1W)	2.057(5)	Co(1)-N(1)	2.124(6)
Co(1)-N(3b)	2.124(7)
Angles
O(1W)-Co(1)-N(1a)	89.8(3)	O(1W)-Co(1)-N(3b)	88.3(3)
O(1W)-Co(1)-N(1)	90.2(3)	N(1)-Co(1)-N(3b)	94.1(3)
O(1W)-Co(1)-N(3c)	91.7(3)	N(1)-Co(1)-N(3c)	85.9(3)

Symmetry codes: (a) −𝑥+2, −𝑦+2, −𝑧; (b) x, −𝑦+5/2, 𝑧−1/2; (c) −𝑥+2, 𝑦−1/2, −𝑧+1/2 for 1; (a) −𝑥+2, −𝑦+2, −𝑧; (b) −𝑥+2, 𝑦+1/2, −𝑧+1/2; (c) x, −𝑦+3/2, 𝑧−1/2 for 2; (a) −𝑥+1, −𝑦+1, −𝑧; (b) x, y, 𝑧−1; (c) −𝑥+1, −𝑦+1, −𝑧+1 for 3.