Research Article

Efficient and Rapid Solvent-Free Acetylation of Alcohols, Phenols, and Thiols Using Catalytic Amounts of Sodium Acetate Trihydrate

Table 3

Competitive acetylation of various functional groups with Ac2O.

EntryProduct 1Product 21 : 2 a

1642479.table.003a642479.table.003a195 : 5
2642479.table.003b642479.table.003b1100 : 1
3642479.table.003c642479.table.003c170 : 30
4642479.table.003d642479.table.003d120 : 80
5642479.table.003eAcOPh10 : 90
6AcSPhAcOPh88 : 12
7AcNHPhAcOPh90 : 10
8AcNHPhAcSPh80 : 20
94-HO-C6H4-NHAc4-AcO-C6H4-NH299 : 1

Determined by GC.