Research Article

Temperature Effects on Retention and Separation of PAHs in Reversed-Phase Liquid Chromatography Using Columns Packed with Fully Porous and Core-Shell Particles

Table 3

Peak characteristics of the 16 PAHs obtained with the Kinetex columns at 16°C.

PAHKinetex
Experimental dataCalculated data
Rs

Naph4.4130.1710.1000.0480.1700.050
Acy5.3730.1870.1090.0530.1850.0555.4
Flu6.9110.2000.1180.0570.2010.0597.9
Ace7.2040.2070.1210.0590.2060.0611.4
Phe7.8780.1760.1030.0510.1750.0523.5
Anth8.3380.1580.0930.0450.1580.0472.7
Fluo9.4940.1670.0980.0480.1670.0497.1
Pyr10.1930.1770.1030.0500.1750.0524.1
Chr12.2320.2890.1700.0830.2890.0858.7
BaA12.5140.2960.1720.0830.2920.0861.0
BbF15.4670.2030.1190.0580.2020.06011.8
BkF15.7400.1990.1170.0580.1990.0591.4
BaP16.3740.1980.1180.0580.2010.0593.2
DiAn17.2920.1780.1040.0510.1770.0524.9
InPy18.3140.1690.1000.0490.1700.0505.8
BePe18.5730.1690.1010.0490.1720.0511.5

(min) was calculated from value to .