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Journal of Chemistry
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2016
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Article
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Tab 3
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Research Article
Temperature Effects on Retention and Separation of PAHs in Reversed-Phase Liquid Chromatography Using Columns Packed with Fully Porous and Core-Shell Particles
Table 3
Peak characteristics of the 16 PAHs obtained with the Kinetex columns at 16°C.
PAH
Kinetex
Experimental data
Calculated data
Rs
Naph
4.413
0.171
0.100
0.048
0.170
0.050
Acy
5.373
0.187
0.109
0.053
0.185
0.055
5.4
Flu
6.911
0.200
0.118
0.057
0.201
0.059
7.9
Ace
7.204
0.207
0.121
0.059
0.206
0.061
1.4
Phe
7.878
0.176
0.103
0.051
0.175
0.052
3.5
Anth
8.338
0.158
0.093
0.045
0.158
0.047
2.7
Fluo
9.494
0.167
0.098
0.048
0.167
0.049
7.1
Pyr
10.193
0.177
0.103
0.050
0.175
0.052
4.1
Chr
12.232
0.289
0.170
0.083
0.289
0.085
8.7
BaA
12.514
0.296
0.172
0.083
0.292
0.086
1.0
BbF
15.467
0.203
0.119
0.058
0.202
0.060
11.8
BkF
15.740
0.199
0.117
0.058
0.199
0.059
1.4
BaP
16.374
0.198
0.118
0.058
0.201
0.059
3.2
DiAn
17.292
0.178
0.104
0.051
0.177
0.052
4.9
InPy
18.314
0.169
0.100
0.049
0.170
0.050
5.8
BePe
18.573
0.169
0.101
0.049
0.172
0.051
1.5
(min) was calculated from value to
.