Temperature Effects on Retention and Separation of PAHs in Reversed-Phase Liquid Chromatography Using Columns Packed with Fully Porous and Core-Shell Particles
Table 4
Linearity, limits of detection (LOD), and quantification (LOQ) of the analytical method with the Kinetex column at 16°C.
PAH
Linearity 1.25–1000 μg L−1
LOD (μg L−1)
LOQ (μg L−1)
Naph
0.9999
0.88
2.95
Acy
1.0000
2.80
9.32
Flu
0.9999
9.16
30.53
Ace
1.0000
2.04
6.80
Phe
0.9999
2.99
9.96
Anth
1.0000
1.32
4.39
Fluo
1.0000
4.08
13.59
Pyr
1.0000
3.09
10.29
Chr
0.9997
2.81
9.37
BaA
0.9998
4.96
16.53
BbF
1.0000
7.43
24.76
BkF
1.0000
6.02
20.07
BaP
0.9999
7.82
26.08
DiAn
1.0000
2.89
9.63
InPy
1.0000
4.53
15.10
BePe
0.9999
7.36
24.54
Prepared solutions with concentration below LOD were not considered.