The CON−H<sup>…+</sup>NH<sub>2</sub> Blue-Shifting H-Bond Stabilizing Effect on <i>Z</i> Secondary Amides and Cyclic System Conformational Rearrangement through an Alkylamine-Chain Migration Pathway

<div>Preparation of dicationic diaryltriazine <b>4</b>. An important system in structure formation with lacking hydrogen bonds in the intermediate is a main driving force towards the <i>Z</i> isomeric form.</div>

Journal of Chemistry

sch3

Scheme 3

Scheme 3: The CON−H<sup>…+</sup>NH<sub>2</sub> Blue-Shifting H-Bond Stabilizing Effect on <i>Z</i> Secondary Amides and Cyclic System Conformational Rearrangement through an Alkylamine-Chain Migration Pathway 

Scheme 3 | The CON−H…+NH2 Blue-Shifting H-Bond Stabilizing Effect on Z Secondary Amides and Cyclic System Conformational Rearrangement through an Alkylamine-Chain Migration Pathway 