Influence of Zn in the CdS Crystal Lattice and Its Impact over the Catalytic Activity in the H<sub>2</sub> Production

<table class="table-group" id="tab4"><tr><td><table class="table"><tr><td class="thead-hr" colspan="5"><hr/></td></tr><tr class="thead"><td class="align_left"></td><td class="align_center">Bulk Zn<sub>0.2</sub>Cd<sub>0.8</sub>S</td><td class="align_center">Bulk Zn<sub>0.2</sub>Cd<sub>0.8</sub>S</td><td class="align_center">Bulk CdS</td><td class="align_center">Bulk CdS</td></tr><tr><td class="thead-hr" colspan="5"><hr/></td></tr><tr><td class="align_left">Preparation method</td><td class="align_center">Sonochemical</td><td class="align_center">Coprecipitation</td><td class="align_center">Sonochemical</td><td class="align_center">Coprecipitation</td></tr><tr><td class="align_left">Morphology</td><td class="align_center">Hierarchical 3D morphology</td><td class="align_center">Hierarchical 3D morphology</td><td class="align_center">Hierarchical 3D morphology</td><td class="align_center">Hierarchical 3D morphology</td></tr><tr><td class="align_left">H<sub>2</sub> production at 5 h (<i>μ</i>mol)</td><td class="align_center">1044</td><td class="align_center">981</td><td class="align_center">308</td><td class="align_center">243</td></tr><tr><td class="align_left"><svg height="14.1649pt" id="M29" style="vertical-align:-5.529pt" version="1.1" viewbox="-0.0498162 -8.6359 26.1602 14.1649" width="26.1602pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z"></path></g><g transform="matrix(.013,0,0,-0.013,8.327,0)"><path d="M593 650H142L136 622C219 616 224 611 209 531L130 120C114 39 108 34 23 28L17 0H501C518 32 557 130 568 158L540 169C519 132 495 93 469 70C439 43 409 35 332 35C272 35 241 37 225 50C211 61 211 89 222 149L253 320H350C441 320 443 312 441 239H471L510 434H481C455 366 448 358 360 358H260L303 572C311 613 312 615 348 615H431C509 615 522 603 532 581C544 555 546 531 545 491L574 493C583 555 592 631 593 650Z"></path></g><g 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246 61 217 61C198 61 186 80 186 122C186 167 206 250 231 294C262 349 288 375 317 387C334 394 358 400 381 400C413 400 439 393 460 386Z"></path></g></svg> (eV)</td><td class="align_center">2.34</td><td class="align_center">2.26</td><td class="align_center">2.21</td><td class="align_center">2.20</td></tr><tr class="table-tr"><td colspan="5"><hr class="tbody-hr"/></td></tr></table></td></tr><tr class="table-fn"><td><div><sup>a</sup>Reaction conditions were <svg height="8.73137pt" id="M30" style="vertical-align:-0.2063904pt" version="1.1" viewbox="-0.0498162 -8.52498 59.9237 8.73137" width="59.9237pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M956 650H736V622C814 613 818 602 804 542C789 471 733 275 691 141H689C628 314 570 476 514 641H485C434 478 377 312 323 142H321C277 284 238 419 199 554C184 605 186 613 259 622V650H16V622C77 615 92 606 117 524C172 346 228 170 281 -11H312C363 151 419 312 475 488H477C528 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<div>Comparison of some characteristics of unsupported and supported Zn<sub>0.2</sub>Cd<sub>0.8</sub>S photocatalysts tested in water-splitting reaction in the same conditions<sup>a</sup>.</div>

Journal of Chemistry

tab4

Table 4

Table 4: Influence of Zn in the CdS Crystal Lattice and Its Impact over the Catalytic Activity in the H<sub>2</sub> Production 

Journal of Chemistry

Influence of Zn in the CdS Crystal Lattice and Its Impact over the Catalytic Activity in the H2 Production

Table 4

Influence of Zn in the CdS Crystal Lattice and Its Impact over the Catalytic Activity in the H₂ Production