Research Article

Solid-Liquid Phase Equilibria of the Quaternary System (LiCl + LiBO2 + Li2B4O7 + H2O) at 308.15 K: Experimental and Theoretical Prediction

Table 5

Pitzer mixing parameters in the quaternary system LiCl − LiBO2 − Li2B4O7 − H2O at 308.15 K.

SpeciesθΨRef.

Cl,B(OH)4−0.1781[12]
Cl,B4O5(OH)42−−0.1500This work
B(OH)4, B4O5(OH)42−0.0620This work
Li+,Cl,B(OH)40.006856[12]
Li+,Cl B4O5(OH)42−0.0233This work
Li+,B(OH)4, B4O5(OH)42−0.0000This work