Journal of Chemistry

Research Article

[Retracted] Modeling of Vapor-Liquid Equilibrium for Electrolyte Solutions Based on COSMO-RS Interaction

Table 7

Correlation of H int data.


System	T/K	Salt-water interaction		Water-salt interaction
System	T/K	dY/kcal.mol^−1a	dP/%^b	dY/kcal.mol^−1a	dP/%^b

BaBr₂	298.15 to 343.15	0.0105	0.0944	0.0024	0.0504
CaBr₂	298.15 to 343.15	0.0001	0.0183	0.0003	0.0077
CaCl₂	298.15 to 343.15	0.0013	0.0258	0.0004	0.0092
CsBr	298.15 to 343.15	0.0044	0.0261	0.0018	0.0385
CsCl	298.15 to 343.15	0.0144	0.0796	0.0015	0.0319
CsI	298.15 to 343.15	0.0005	0.0037	0.0007	0.6001
K₂SO₄	298.15 to 343.15	0.0072	0.0216	0.0009	0.0186
KBr	298.15 to 343.15	0.0031	0.0217	0.0015	0.0321
KCl	298.15 to 343.15	0.0073	0.0427	0.0021	0.0425
KI	298.15 to 343.15	0.0053	0.0423	0.0007	0.0172
LiCl	298.15 to 343.15	0.0067	0.1118	0.0029	0.0682
MgCl₂	298.15 to 343.15	0.0254	0.8672	0.0029	0.0693
MgSO₄	298.15 to 343.15	0.0408	2.7068	0.0021	0.0517
Na₂SO₄	298.15 to 343.15	0.0124	0.0688	0.0009	0.0187
NaBr	298.15 to 343.15	0.0034	0.0319	0.0024	0.0531
NaCl	298.15 to 343.15	0.0081	0.0614	0.0015	0.0335
NaI	298.15 to 343.15	0.0032	0.0369	0.0031	0.0699
RbCl	298.15 to 343.15	0.0183	0.0995	0.0031	0.0645
SrCl₂	298.15 to 343.15	0.0176	0.1568	0.0007	0.0147
ZnCl₂	298.15 to 343.15	0.0098	0.6254	0.0037	0.0812
Average		0.010	0.257	0.0018	0.0689

^a, where N is the number of data points. ^b, where N is the number of data points. P_exp represents the experimental pressure and P_cal represents the calculated pressure.