Research Article
Determination of Polycyclic Aromatic Hydrocarbons in Tea Infusions Samples by High Performance Liquid Chromatography with Fluorimetric Detection
Table 1
Analytical characteristics of chromatographic method.
| Peak | Polycyclic aromatic hydrocarbons | Retention time (min) ± standard deviation (sample = 10) | Linearity range (ng/L) | Regression coefficient | Detection limit (signal/noise = 3) (ng/L) |
| 1 | Naphthalene | | 2.1–500 | 0.9998 | 0.63 | 2 | Acenaphtene | | 5.3–300 | 0.9998 | 1.60 | 3 | Fluorene | | 5.0–30 | 0.9509 | 1.50 | 4 | Phenanthrene | | 1.7–40 | 0.9963 | 0.35 | 5 | Anthracene | | 0.66–20 | 0.9999 | 0.20 | 6 | Fluoranthene | | 4.2–15 | 0.9930 | 1.25 | 7 | Pyrene | | 7.0–100 | 0.9984 | 2.10 | 8 | Benz[a]anthracene | | 1.5–30 | 0.9962 | 0.45 | 9 | Chrysene | | 1.5–50 | 0.9970 | 0.45 | 10 | Benzo[b]fluoranthene | | 6.7–20 | 0.9938 | 2.00 | 11 | Benzo[k]fluoranthene | | 0.83–20 | 0.9965 | 0.25 | 12 | Benzo[a]pyrene | | 2.1–50 | 0.9948 | 0.63 | 13 | Dibenz[a,h]anthracene | | 2.0–200 | 0.9973 | 0.60 | 14 | Benzo[ghi]perylene | | 4.6–80 | 0.9969 | 1.40 | 15 | Indeno[1,2,3-cd]pyrene | | 33–50 | 0.9944 | 10 |
|
|