Fabrication of Nanoparticle-Stacked 1,1-Diamino-2,2-Dinitroethylene (FOX-7) Microspheres with Increased Thermal Stability

<table class="table-group" id="tab2"><tr><td><table class="table"><tr><td class="thead-hr" colspan="6"><hr/></td></tr><tr class="thead"><td class="align_left"></td><td class="align_center"><svg height="12.2532pt" id="M39" style="vertical-align:-3.29108pt" version="1.1" viewbox="-0.0498162 -8.96212 12.1667 12.2532" width="12.1667pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M620 675H597C578 656 570 650 541 650H144C112 650 104 653 94 675H72C59 618 42 552 23 493L53 491C71 534 88 564 105 585C124 608 144 615 238 615H290L197 121C182 40 174 34 88 28L82 0H361L367 28C275 34 266 38 281 121L374 615H441C522 615 543 608 553 583C562 560 566 531 565 493L597 494C603 551 612 629 620 675Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,7.176,3.132)"><path d="M460 334C460 396 434 451 378 451C330 451 241 408 148 300H146L237 679C241 697 241 710 232 710C213 710 153 684 67 675L66 646H95C141 646 145 642 134 595L39 170C23 97 31 54 46 33C64 8 100 -12 137 -12C178 -12 234 3 298 43C391 101 460 222 460 334ZM371 320C371 204 316 89 248 51C230 41 208 37 192 37C143 37 102 72 119 166C124 194 129 215 135 235C202 323 298 392 335 392C353 392 371 372 371 320Z"></path></g></svg> (°C)</td><td class="align_center"><svg height="14.3267pt" id="M40" style="vertical-align:-5.36458pt" version="1.1" viewbox="-0.0498162 -8.96212 12.5869 14.3267" width="12.5869pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M620 675H597C578 656 570 650 541 650H144C112 650 104 653 94 675H72C59 618 42 552 23 493L53 491C71 534 88 564 105 585C124 608 144 615 238 615H290L197 121C182 40 174 34 88 28L82 0H361L367 28C275 34 266 38 281 121L374 615H441C522 615 543 608 553 583C562 560 566 531 565 493L597 494C603 551 612 629 620 675Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,7.176,3.132)"><path d="M169 380V459C122 440 66 423 24 416V392C86 384 90 382 90 317V-135C90 -201 81 -207 17 -213V-240H253V-213C176 -207 169 -201 169 -125V6C182 -1 208 -11 238 -12C368 12 487 109 487 260C487 358 421 449 310 449C298 449 279 444 261 433L169 380ZM169 346C196 367 237 389 269 389C341 389 403 329 403 221C403 109 347 37 263 37C228 37 191 53 169 76V346Z"></path></g></svg> (°C)</td><td class="align_center"><svg height="11.5512pt" id="M41" style="vertical-align:-0.2063999pt" version="1.1" viewbox="-0.0498162 -11.3448 20.7019 11.5512" width="20.7019pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z"></path></g><g transform="matrix(.013,0,0,-0.013,8.327,0)"><path d="M449 634C442 637 425 643 405 650C376 660 341 666 307 666C181 666 98 590 98 485C98 400 170 343 215 310L246 288C307 243 343 204 343 147C343 67 291 18 219 18C104 18 61 124 51 202L23 199C28 124 27 71 27 47C47 22 122 -16 204 -16C324 -16 428 60 428 174C428 256 379 309 307 360L276 382C223 419 179 455 179 516C179 576 221 632 293 632C379 632 410 564 418 487L448 490C446 536 446 592 449 634Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,20.053,-5.741)"><path d="M-170 599L-228 617L-442 -75L-384 -93L-170 599Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,14.463,-5.741)"><path d="M556 331V384H55V331H556ZM556 140V193H55V140H556Z"></path></g></svg> (J/mol)</td><td class="align_center"><svg height="11.3946pt" id="M42" style="vertical-align:-0.04979992pt" version="1.1" viewbox="-0.0498162 -11.3448 25.5039 11.3946" width="25.5039pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z"></path></g><g transform="matrix(.013,0,0,-0.013,8.327,0)"><path d="M828 650H570L564 622C646 614 650 609 634 524L604 366H253L281 524C296 608 308 615 382 622L388 650H132L126 622C211 615 214 609 198 524L121 122C106 42 102 35 23 28L17 0H276L282 28C196 35 191 40 206 122L243 324H597L559 123C544 42 537 35 452 28L446 0H710L716 28C632 35 628 43 643 122L719 524C735 610 741 615 822 622L828 650Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,24.84,-5.741)"><path d="M-170 599L-228 617L-442 -75L-384 -93L-170 599Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,19.25,-5.741)"><path d="M556 331V384H55V331H556ZM556 140V193H55V140H556Z"></path></g></svg> (kJ/mol)</td><td class="align_center"><svg height="11.5512pt" id="M43" style="vertical-align:-0.2063999pt" version="1.1" viewbox="-0.0498162 -11.3448 23.4683 11.5512" width="23.4683pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z"></path></g><g transform="matrix(.013,0,0,-0.013,8.327,0)"><path d="M673 297H417L411 270C517 261 522 258 506 183L487 92C476 38 428 19 360 19C207 19 123 132 123 287C123 472 243 631 441 631C557 631 617 583 617 469L647 472C650 545 655 604 658 632C625 643 554 666 467 666C201 666 23 502 23 278C23 90 156 -16 339 -16C410 -16 501 6 569 24C566 43 567 70 573 101L589 183C604 259 607 262 667 271L673 297Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,22.809,-5.741)"><path d="M-170 599L-228 617L-442 -75L-384 -93L-170 599Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,17.219,-5.741)"><path d="M556 331V384H55V331H556ZM556 140V193H55V140H556Z"></path></g></svg> (kJ/mol)</td></tr><tr><td class="thead-hr" colspan="6"><hr/></td></tr><tr><td class="align_left">FOX-7</td><td class="align_center">223.24</td><td class="align_center">221.79</td><td class="align_center">306.53</td><td class="align_center">281.36</td><td class="align_center">129.64</td></tr><tr><td class="align_left">Sample 1</td><td class="align_center">221.77</td><td class="align_center">220.34</td><td class="align_center">100.00</td><td class="align_center">207.04</td><td class="align_center">157.69</td></tr><tr><td class="align_left">Sample 2</td><td class="align_center">241.88</td><td class="align_center">240.18</td><td class="align_center">72.87</td><td class="align_center">202.40</td><td class="align_center">165.00</td></tr><tr class="table-tr"><td colspan="6"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

<div>Thermodynamic property data of the samples.</div>

Journal of Nanomaterials

tab2

Table 2

Table 2: Fabrication of Nanoparticle-Stacked 1,1-Diamino-2,2-Dinitroethylene (FOX-7) Microspheres with Increased Thermal Stability 