Size, Shape, and Material Effects in Ferroelectric Octahedral Nanoparticles

<div>(a) The FE bulk energy (<span class="nowrap"><svg height="11.9087pt" id="M65" style="vertical-align:-3.2728pt" version="1.1" viewbox="-0.0498162 -8.6359 23.7318 11.9087" width="23.7318pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M584 650H137L131 622C214 614 217 612 200 521L125 127C109 41 101 35 23 28L17 0H288L294 28C201 35 193 42 209 128L242 309H348C440 309 442 300 443 226H471L510 422H482C452 354 449 348 357 348H251L295 575C302 609 304 615 338 615H426C502 615 517 604 526 581C534 560 536 524 537 492L565 494C574 554 583 631 584 650Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,6.786,3.132)"><path d="M152 404V712C115 698 54 683 7 677V654C71 648 73 642 73 579V24C128 -2 179 -12 220 -12C353 -12 471 92 471 238C471 357 381 449 274 449C262 449 249 446 233 439L152 404ZM152 374C170 384 202 393 230 393C313 393 382 326 382 213C382 97 330 26 246 26C194 26 165 62 158 81C154 91 152 101 152 116V374Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,11.308,3.132)"><path d="M518 50L491 51C452 54 444 60 444 110V444C429 441 405 437 377 434C348 430 314 427 287 426V403L323 397C356 392 365 386 365 333V99C331 66 293 51 257 51C212 51 169 75 169 164V299C169 366 169 413 172 444C156 441 128 437 101 433C75 430 50 427 29 426V403L57 397C82 391 90 386 90 333V137C90 29 147 -12 214 -12C241 -12 262 -4 291 13S342 48 365 65V-6L371 -12C390 -7 415 1 441 8C468 15 496 21 518 24V50Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,16.186,3.132)"><path d="M238 0V26C174 32 166 38 166 104V712C132 700 70 683 18 677V653C81 647 87 645 87 577V104C87 38 78 32 15 26V0H238Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,18.534,3.132)"><path d="M513 0V26C475 28 448 43 413 81C379 116 277 234 258 264C301 314 319 334 344 359C383 396 404 407 473 418V443L269 434V408C317 403 320 395 299 364C280 337 250 298 228 276C213 260 195 247 165 241V712C126 699 69 682 21 677V653C82 648 87 642 87 576V104C87 40 81 32 14 26V0H237V26C173 32 165 38 165 104V215C171 217 176 218 181 218C189 218 198 212 212 196C267 129 330 49 376 -2L513 0Z"></path></g></svg>)</span> of PT/ST and BT/ST systems plotted as a function of octahedral nanoparticle inclusion’s side length <span class="nowrap"><svg height="9.49473pt" id="M66" style="vertical-align:-0.2063999pt" version="1.1" viewbox="-0.0498162 -9.28833 3.60972 9.49473" width="3.60972pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M238 681C243 705 239 712 230 712C217 712 156 682 75 674L70 648H105C148 648 153 641 144 598L39 110C18 11 35 -12 55 -12C90 -12 166 36 221 103L205 125C174 93 130 65 118 65C112 65 108 68 114 96L238 681Z"></path></g></svg>.</span> (b) The profile of <svg height="11.439pt" id="M67" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 15.4841 11.439" width="15.4841pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M162 -163V703H101V-163H162Z"></path></g><g transform="matrix(.013,0,0,-0.013,3.419,0)"><path d="M652 479C652 619 526 650 406 650H138L130 614C208 609 215 596 197 503L126 139C109 51 102 42 24 37L16 0H339L347 37C252 45 241 51 258 139L284 277L368 260C373 259 385 259 394 259C541 269 652 344 652 479ZM511 489C511 400 454 305 358 305C334 305 308 312 294 316L337 544C346 591 347 594 358 599C367 603 381 607 403 607C468 607 511 573 511 489Z"></path></g><g transform="matrix(.013,0,0,-0.013,11.94,0)"><path d="M162 -163V703H101V-163H162Z"></path></g></svg> along a line perpendicular to the vortex core in octahedral nanoparticles with vortex-like polarization textures.</div>

Journal of Nanomaterials

fig2

Figure 2

Figure 2: Size, Shape, and Material Effects in Ferroelectric Octahedral Nanoparticles 