Review Article

Graphene and g-C3N4-Based Gas Sensors

Table 10

The performances of nanocomposites based on g-CN for gas sensor applications.

MaterialMethodResponse/GasResponse/recovery time (s)ppm levelOperation T (°C)Detection limitCommentRef.

TiO2Spray pyrolysis techniqueRa/Rg = 25%/H2S∼52/601500450UThe improvement in the detection performance of the sensor is due to the introduction of 10% of the g-CN nanosheets[103]
Ra/Rg = 22%/CO245/55
g-CN (10 wt%)/TiO2Ra/Rg = 67%/H2S∼30/52
Ra/Rg = 88%/CO235/27
SnO2Hydrothermal methodRa/Rg = 13.4%/acetic acid94/1601000230°CUImprovement of the operating temperature and the sensitivity by introduction of 10 wt% of g-CN in SnO2[58]
10 wt% of g-CN-SnO2Ra/Rg = 87.7%/CH3COOHU185°C0.1 ppm
g-CN-SnO2One-step calcination methodVg/Va = 83%/acetone7/8500380°C67 ppbA significant improvement in sensor performance by calcining melamine/SnO2 powder for 3 hours[14]
5%Pd/SnO2/5%g-CNHydrothermal method(Rg-Ra)/Ra = 90.5%/CO10/131000125°C75 ppmg-CN-5% nanosheets with SnO2 nanoparticles effectively improved the response of the gas sensors towards CO[25]
2 wt% g-CN-WO3Hydrothermal methodRa/Rg = 58.2%/acetone53/291000310°C0.5 ppmA gas sensor based on 2% g-CN composite shows a higher response to acetone than pure WO3[125]
10 wt% g-CN/MgFe2O4One-step solvothermal methodRa/Rg = 275/acetone49/29500320°C30 ppbThe introduction of 10% of g-CN nanosheets in MgFe2O4 improves their detection performance[126]
Gr/g-CNDrop coating method(Rg-Ra)/Ra = 42%/NO2U5100°C600 ppbGraphitic carbon nitride nanosheets with 15% of g-CN exhibit high detection performance compared to bulk g-CN and pure graphene[127]
10 wt% g-CN/ZnOSynthesized via ultrasonic mixing and subsequent calcination processRg/Ra = 44.8%/NO2142/1907U38 ppmDetection performance is activated by LED light sources. 460 nm LED (12.7 W/m2)[128]

“U”: unavailable citation: it is not cited in the study. Vg/Va: electric voltages in the target gases and atmospheric air, respectively. Ra/Rg: electric resistances in the atmospheric air and target gases, respectively.