Kinetic Analysis for Macrocyclizations Involving Anionic Template at the Transition State

Figure 9

Concentration of the reactants, products, and reaction intermediates versus time for kinetic model 5. [A]₀ = [B]₀ = 0.005 M, [Br⁻]₀ = 10⁻¹² M, 𝑘_1𝑐 = 4000 M⁻¹ min⁻¹ and 𝑘_2𝑐 = 200 M⁻¹ min⁻¹.