Review Article

Microplastics in the Ecosystem: A Systematic Review of the Methods for Their Detection and Removal

Table 3

Methods applied in the removal of microplastics.

MP purification technologiesRemoval efficiencyAdvantagesLimitationReference

Physical methods of removal
Rapid sand filtration (RSF)97%This filter removes suspended particles, microorganisms, and nutrients. It is effective in filtering small particlesIt is necessary to add a coagulant to improve the adhesive ability[109]
Dissolved air flotation (DAF)95%Low investment costs due to compact design, short retention time, and small dimensions of flocculation and flotation chambersThere are concerns about how interactions between bubbles/particles (aggregates), particularly in relation to adhesion through hydrophobic forces, work[68]
Disc filter (DF)89.7%It has lower energy consumption, high resistance to various chemical contaminants, and is effective in reducing the presence of microplastics in wastewater effluentsNeeds to be cleaned through high-pressure backwashing or using sodium hypochlorite to remove sludge buildup[110, 111]
Ultrafiltration86–97.96%High retention capacity, optimal recovery rate, high-speed filtration, versatility in different application contexts, reduced cost, and absence of phase transferWater passing through the membrane forms a concentrated polarization layer, which negatively affects filtration efficiency due to fouling[112, 113]
Dynamic membrane (DM)99%Low resistance to filtration, low transmembrane pressure, ease of operation, and absence of chemical treatmentDue to its oily nature, frequent cleaning is necessary to prevent excessive membrane fouling and sediment accumulation, which leads to high-energy consumption[99]
Magnetic nanoparticle method<92%By removing organic, inorganic, microbial, and microplastic pollutants from water, the magnetic compound can be easily retrieved using a conventional magnetIt causes fragmentation of more fragile particulate matter and requires filtration suitable only for small water volumes[103, 114, 115]

Chemical methods of removal
Coagulation/flocculation61%Suitable for removing small microparticles, operating under adjustable conditions, and utilizing simple mechanical mechanismsChemicals must be added to the medium for small microplastics[116]
Electrocoagulation>90%No risk of contamination, effective for small particle removal, cost-efficient, and flexible for automation while minimizing sludgeRepeated replacement of sacrificial anodes is necessary to prevent cathode passivation. In addition, this product is not suitable for use in areas without access to electricity[100]
Micromotors67%Water is utilized as a nontoxic source for the effective removal of suspended particles and microplastics, while sunlight is harnessed as a renewable energy resourceIt takes a chain of magnetic clusters to overcome obstacles and lacks selectivity[117, 118]
Microsubmarines70%Sustainability is demonstrated through recycling and the elimination of oil and microplastic pollutionMicrosubmarines have limited transportation capacity, thus requiring the combination of multiple microsubmarines in order to achieve sufficient capacity[119, 120]

Biological methods of removal
Oxidation ditches97%Compared to other biological treatment methods, sludge generation is reduced and less energy is consumed during the processThis method is highly efficient in smaller facilities but requires more space than traditional treatment plants[108, 121]
Anaerobic, anoxic, and aerobic (A2O)72–98%High organic loads can be handled with minimal sludge productionThe anaerobic treatment process requires sufficient time to become effective[104, 122]
Membrane bioreactors (MBR)99.9%It is capable of removing high levels of biological oxygen demand (BOD) and chemical oxygen demand (COD) from a variety of wastewater compositionsOne of the major issues is the inability to eliminate contaminants that are resistant to removal[123, 124]
Sequential batch reactor (SBR)92.74%It offers an affordable solution for achieving lower levels of effluent contaminants, allowing for easy expansion and simple operation with low capital costsEffective aeration control is essential for optimal SBR efficiency, and the presence of sand can hinder this process[125]
Conventional activated sludge (CAS)95–99.9%The treatment is cost-effective, adaptable to various tributary concentrations, and resistant to changesThe tank’s long residence times, large settling surface, and high-energy consumption result in costly sludge processing and disposal[98, 126]
Adsorption on green microalgae94.5The cut surfaces show a strong ability to attract small microplastic particles, and the selection is based on the surface charge of these microplasticsNonreusable method, with microplastics that chemically adhere to the surface, potentially contaminating it[127, 128]
Fungal degradation59% of the weight of the MPsNatural decomposition through enzymes produced by fungiThe removal of MPs takes a long period, as it only becomes significant after an incubation period of 280 days at a temperature of 25°C[129, 130]
Bacterial degradation20.4–97%The application of bacteria is highly selective, reducing the likelihood of generating harmful byproducts. Furthermore, it consumes less energy and is more cost-effective than chemical procedures and applicable in a variety of contextsSometimes, the elimination of contaminants is not complete, and the process can be prolonged. Furthermore, it can be difficult to identify the right group of bacteria for efficient removal of MPs[131133]