| | No. | RT (min) | Exptl. mass (m/z) | Calc. mass (m/z) | Difference (ppm) | Adducts | Chemical formula | Tentative identification | Fragments |
| | 1 | 0.76 | 481.0635 | 481.0618 | 3.5 | M-H | C20H18O14 | HHDP hexoside | 301,302 | | 2 | 1.16 | 191.0192 | 191.0192 | 0.0 | M-H | C6H8O7 | Citric acid | 111 | | 3 | 1.40 | 481.0635 | 481.0618 | 3.5 | M-H | C20H18O15 | HHDP hexoside isomers | 301,302 | | 4 | 2.28 | 331.0683 | 331.0665 | 5.4 | M-H | C13H16O10 | 1-O-Galloyl-beta-D-glucose | 169 | | 5 | 2.61 | 609.1261 | 609.1244 | 2.8 | M-H | C30H26O14 | Gallocatechin-epigallocatechin | | | 6 | 2.75 | 305.0666 | 305.0661 | 1.6 | M-H | C15H14O7 | Epigallocatechin | | | 7 | 2.82 | 541.0251 | 541.0254 | -0.6 | M-2H | C48H28O30 | Punicalagin | 275, 301, 532, 601, 781 | | 8 | 2.94 | 541.0251 | 541.0254 | -0.6 | M-2H | C48H28O30 | Punicalagin isomers | 275, 301, 532, 601, 781 | | 9 | 2.99 | 449.1060 | 449.1084 | -5.3 | M+ | C21H21O11 | Cyanidin 3-O-beta-D-glucoside | 287 | | 10 | 3.06 | 799.0631 | | | M-H | | Ellagic acid derivative | 301, 479, 781 | | 11 | 3.15 | 289.2713 | 289.0712 | 0.3 | M-H | C15H14O6 | Catetein | 179,205,245 | | 12 | 3.19 | 633.0729 | 633.0728 | 0.2 | M-H | C27H22O18 | Corilagin | 301, 463 | | 13 | 3.28 | 463.0522 | 463.0513 | 1.9 | M-H | C20H16O13 | Ellagic acid hexoside | 301 | | 14 | 3.37 | 951.0758 | 951.0740 | 1.9 | M-H | C41H28O27 | Galloyl-HHDP-DHHDP-hex (granatin B) | 301, 445, 613, 933 | | 15 | 3.54 | 433.0406 | 433.0407 | -0.2 | M-H | C19H14O12 | Ellagic acid pentoside | 301 | | 16 | 3.56 | 447.0583 | 447.0564 | 4.3 | M-H | C20H16O12 | Ellagic acid deoxyhexoside | 301 | | 17 | 3.69 | 300.9993 | 300.9984 | 3.0 | M-H | C14H6O8 | Ellagic acid | 185, 229, 257, 283 | | 18 | 3.74 | 595.1638 | 595.1663 | -4.3 | M+ | C27H31O15 | Cyanidin-3-O-rutinoside | 287,449 | | 19 | 3.85 | 447.0933 | 447.0927 | 1.3 | M-H | C21H20O11 | Kaempferol 3-O-glucoside | 227,255,284 | | 20 | 4.02 | 447.0933 | 447.0927 | 1.3 | M-H | C21H20O11 | Quercetin hexoside | 151, 179, 301 | | 21 | 4.05 | 435.1287 | 435.1291 | -0.9 | M-H | C21H24O10 | Phlorizin | 273 | | 22 | 4.25 | 435.1287 | 435.1291 | -0.9 | M-H | C21H24O10 | Phlorizin isomers | 167, 273 | | 23 | 8.84 | 487.3441 | 487.3423 | 3.7 | M-H | C30H48O5 | Asiatic acid | | | 24 | 9.35 | 485.3272 | 485.3267 | 1.0 | M-H | C30H46O5 | Actinidic acid | | | 25 | 9.49 | 487.3441 | 487.3423 | 3.7 | M-H | C30H48O6 | Asiatic acid isomers | |
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